2021

Most recent scientific publications

R A Pérez-Camargo, G Liu, L Meabe, Y Zhao, H Sardon, A J Müller, D Wang

Using Successive Self-Nucleation and Annealing to Detect the Solid–Solid Transitions in Poly (hexamethylene carbonate) and Poly (octamethylene carbonate)

Macromolecules 2021,  XXXX, XXX, XXX-XXX

https://doi.org/10.1021/acs.macromol.1c01856

N Fanjul-Mosteirín, R Aguirresarobe, N Sadaba, A Larrañaga, E Marin, J Martin, N Ramos-Gomez, M C Arno, H Sardon, A P Dove

Crystallization-Induced Gelling as a Method to 4D Print Low-Water-Content Non-isocyanate Polyurethane Hydrogels

Chemistry of materials 2021, 33 (18), 7194–7202

https://doi.org/10.1021/acs.chemmater.1c00913

H Sardon, D Mecerreyes, A Basterretxea, L Avérous, C Jehanno

From Lab to Market: Current Strategies for the Production of Biobased Polyols

ACS Sustainable Chemistry & Engineering 2021, 9 (32), 10664-10677

https://doi.org/10.1021/acssuschemeng.1c02361

R A Pérez-Camargo, G Liu, L Meabe, Y Zhao, H Sardon, D Wang, A J Müller

Solid–Solid Crystal Transitions (δ to α) in Poly(hexamethylene carbonate) and Poly(octamethylene carbonate)

Macromolecules 2021,  54 (15), 7258-7268.

https://doi.org/10.1021/acs.macromol.1c01188

A Gomez-Lopez, S Panchireddy, B Grignard, I Calvo, C Jerome, C Detrembleur, H Sardon

Poly (hydroxyurethane) Adhesives and Coatings: State-of-the-Art and Future Directions

ACS Sustainable Chem. Eng. 2021, 9, 29, 9541–9562

https://doi.org/10.1021/acssuschemeng.1c02558

M Safari, I Otaegi, N Aramburu, G Guerrica-Echevarria, A Martínez Martínez de Ilarduya, H Sardon, A J Müller

Synthesis, Structure, Crystallization and Mechanical Properties of Isodimorphic PBS-ran-PCL Copolyesters

Polymers 2021, 13(14), 2263

https://doi.org/10.3390/polym13142263

X Lopez de Pariza, E Cordero Jara, N Zivic, F Ruipérez, T E Long, H Sardon

Novel imino- and aryl-sulfonate based photoacid generators for the cationic ring-opening polymerization of ε-caprolactone

Polym. Chem., 2021, 12, 4035-4042

https://doi.org/10.1039/D1PY00734C

J L Olmedo-Martínez, M Pastorio, E Gabirondo, A Lorenzetti, H Sardon, D Mecerreyes, A J Müller

Polyether Single and Double Crystalline Blends and the Effect of Lithium Salt on Their Crystallinity and Ionic Conductivity

Polymers 2021, 13(13), 2097

https://doi.org/10.3390/polym13132097

O Llorente, A Agirre, I Calvo, M Olaso, R Tomovska, H Sardon

Exploring the advantages of oxygen-tolerant thiol-ene polymerization over conventional acrylate free radical photopolymerization processes for pressure-sensitive adhesives

Polymer Journal 2021, XXXX, XXX, XXX-XXX

https://doi.org/10.1038/s41428-021-00520-z

A Basterretxea, E Gabirondo, C Jehanno, H Zhu, O Coulembier, D Mecerreyes, H Sardon

Stereoretention in the Bulk ROP of l-Lactide Guided by a Thermally Stable Organocatalyst

Macromolecules 2021, 54, 13, 6214–6225

https://doi.org/10.1021/acs.macromol.1c01060

S Marina, A D Scaccabarozzi, E Gutierrez‐Fernandez, E Solano, A Khirbat, L Ciammaruchi, A Iturrospe, A Balzer, L Yu, E Gabirondo, X Monnier, H Sardon, T D Anthopoulos, M Caironi, M Campoy‐Quiles, C Müller, D Cangialosi, N Stingelin, Jaime Martin

Polymorphism in Non‐Fullerene Acceptors Based on Indacenodithienothiophene

Advanced Functional Materials 2021, 31, 29, 2103784

https://doi.org/10.1002/adfm.202103784

E Sanchez-Rexach, P T Smith, A Gomez-Lopez, M Fernandez, A L Cortajarena, H Sardon, A Nelson

3D-Printed Bioplastics with Shape-Memory Behavior Based on Native Bovine Serum Albumin

ACS Appl. Mater. Interfaces 2021, 13, 16, 19193–19199

https://doi.org/10.1021/acsami.0c22377

C Jehanno, J Demarteau, D Mantione, M C Arno, F Ruiperez, J L Hendrick, A P Dove, H Sardon

Selective Chemical Upcycling of Mixed Plastics Guided by a Thermally Stable Organocatalyst

Angewandte Chemie International Edition 60 (12), 6710-6717

https://doi.org/10.1002/anie.202014860

M Riechers, L Fanini, A Apicella, C B Galván, E Blondel, B Espiña, S Kefer, …

Plastics in our ocean as a transdisciplinary challenge

Marine Pollution Bulletin 164, 112051

https://doi.org/10.1016/j.marpolbul.2021.112051

A Gomez-Lopez, B Grignard, I Calvo, C Detrembleur, H Sardon

Synergetic Effect of Dopamine and Alkoxysilanes in Sustainable Non-Isocyanate Polyurethane Adhesives

Macromolecular Rapid Communications 42 (3), 2000538

https://doi.org/10.1002/marc.202000538

R H Aguirresarobe, S Nevejans, B Reck, L Irusta, H Sardon, J M Asua, N Ballard

Healable and self-healing polyurethanes using dynamic chemistry

Progress in Polymer Science 114, 101362

https://doi.org/10.1016/j.progpolymsci.2021.101362

A Gallastegui, E Gabirondo, F Elizalde, N Aranburu, D Mecerreyes, H Sardon

Chemically recyclable glycerol-biobased polyether thermosets

European Polymer Journal 143, 110174

https://doi.org/10.1016/j.eurpolymj.2020.110174

V Montagna, J Takahashi, M Y Tsai, T Ota, N Zivic, S Kawaguchi, T Kato, M Tanaka, H Sardon, K Fukushima

Methoxy-Functionalized Glycerol-Based Aliphatic Polycarbonate: Organocatalytic Synthesis, Blood Compatibility, and Hydrolytic Property

ACS Biomaterials Science & Engineering 7 (2), 472-481

https://doi.org/10.1021/acsbiomaterials.0c01460

X Monnier, S Marina, X Lopez de Pariza, H Sardón, J Martin, D Cangialosi

Physical Aging Behavior of a Glassy Polyether

Polymers 13 (6), 954

https://doi.org/10.3390/polym13060954

E Gabirondo, B Melendez-Rodriguez, C Arnal, J M Lagaron, A Martínez de Ilarduya, H Sardon, S Torres-Giner

Organocatalyzed closed-loop chemical recycling of thermo-compressed films of poly (ethylene furanoate)

Polymer Chemistry 12 (10), 1571-1580

https://doi.org/10.1039/D0PY01623C

2020

K O’Harra, N Sadaba, M Irigoyen, F Ruipérez, R Aguirresarobe, H Sardon, J Bara

Nearly Perfect 3D Structures Obtained by Assembly of Printed Parts of Polyamide Ionene Self-Healing Elastomer

ACS Applied Polymer Materials 2020, 2, 11, 4352–4359

https://doi.org/10.1021/acsapm.0c00799

S M Morozova, E I Lozinskaya, H Sardon, F Suárez-García, P S.Vlasov, R Vaudemont, Y S Vygodskii, A S Shaplov

Ionic Polyureas—A Novel Subclass of Poly(Ionic Liquid)s for CO2 Capture

Membranes 2020, 10, 240

https://doi.org/10.3390/membranes10090240

E Sanchez-Rexach, T G Johnston, C Jehanno, H Sardon, A Nelson

Sustainable Materials and Chemical Processes for Additive Manufacturing

Chem. Mater. 2020, 32, 17, 7105–7119

https://doi.org/10.1021/acs.chemmater.0c02008

K Saito, C Jehanno, L Meabe, J L Olmedo-Martínez, D Mecerreyes, K Fukushima, H Sardon

From plastic waste to polymer electrolytes for batteries through chemical upcycling of polycarbonate

J Mater Chem A 2020, 8, 13921-13926

https://doi.org/10.1039/D0TA03374J

J Demarteau, I Olazabal, C Jehanno, H Sardon

Aminolytic upcycling of poly(ethylene terephthalate) wastes using a thermally-stable organocatalyst

Polymer Chem 2020, 11, 4875-4882

https://doi.org/10.1039/D0PY00067A

L Sangroniz, A Sangroniz, L Meabe, A Basterretxea, H Sardon, D Cavallo, A J Müller

Chemical Structure Drives Memory Effects in the Crystallization of Homopolymers

Macromolecules 2020, 53, 12, 4874–4881

https://doi.org/10.1021/acs.macromol.0c00751

A Basterretxea, X Lopez de Pariza, E Gabirondo, S Marina, J Martin, A Etxeberria, D Mecerreyes, H Sardon

Synthesis and Characterization of Fully Biobased Copolyether Polyols

Ind. Eng. Chem. Res. 2020, 59, 23, 10746–10753

https://doi.org/10.1021/acs.iecr.0c00723

J Demarteau, K E O’Harra, J E Bara, H Sardon

Valorization of Plastic Wastes for the Synthesis of Imidazolium Based Self‐Supported Elastomeric Ionenes

ChemSusChem 2020, 13, 12, 3122-3126

https://doi.org/10.1002/cssc.202000505

J Huang, C Jehanno, J C Worch, F Ruipérez, H Sardon, A P Dove, O Coulembier

Selective Organocatalytic Preparation of Trimethylene Carbonate from Oxetane and Carbon Dioxide

ACS Catal. 2020, 10, 10, 5399–5404

https://doi.org/10.1021/acscatal.0c00689

A Gomez-Lopez, B Grignard, I Calvo, C Detrembleur, H Sardon

Monocomponent Non-isocyanate Polyurethane Adhesives Based on a Sol–Gel Process

ACS Appl. Polym. Mater. 2020, 2, 5, 1839–1847

https://doi.org/10.1021/acsapm.0c00062

N Zivic, N Sadaba, N Almandoz, F Ruipérez, D Mecerreyes, H Sardon

Thioxanthone-Based Photobase Generators for the Synthesis of Polyurethanes via the Photopolymerization of Polyols and Polyisocyanates

Macromolecules 2020, 53, 6, 2069–2076

https://doi.org/10.1021/acs.macromol.9b02648

C Jehanno, J Demarteau, D Mantione, M C Arno, F Ruipérez, J L Hedrick, A P Dove, H Sardon

Synthesis of Functionalized Cyclic Carbonates through Commodity Polymer Upcycling

ACS Macro Lett. 2020, 9, 4, 443–447

https://doi.org/10.1021/acsmacrolett.0c00164

E Gabirondo, A Sangroniz, A Etxeberria, Se Torres-Giner, H Sardon

Poly (hydroxy acids) derived from the self-condensation of hydroxy acids: from polymerization to end-of-life options

Polym. Chem., 2020, 11, 4861-4874

https://doi.org/10.1039/D0PY00088D

I Arandia, LMeabe, N Aranburu, H Sardon, D Mecerreyes, A J Müller

Influence of Chemical Structures on Isodimorphic Behavior of Three Different Copolycarbonate Random Copolymer

Series Macromolecules 2020, 53, 2, 669–681

https://doi.org/10.1021/acs.macromol.9b02078

I Flores, A Martínez de Ilarduya, H Sardon, A J Müller, S Muñoz-Guerra*

ROP and crystallization behaviour of partially renewable triblock aromatic-aliphatic copolymers derived from L-lactide

Eur. Polym. J. 2020, 122, 109321

https://doi.org/10.1016/j.eurpolymj.2019.109321

2019

C Jehanno, L Mezzasalma, H Sardon, F Ruipérez, O Coulembier and D Taton

Benzoic Acid as an Efficient Organocatalyst for the Statistical Ring-Opening Copolymerization of ε-Caprolactone and L-Lactide: A Computational Investigation

Macromolecules 2019, 52, 23, 9238–9247

https://doi.org/10.1021/acs.macromol.9b01853

 

J P K. Tan, J Tan, N Park, K Xu, E D Chan, C Yang, V A Piunova, Z Ji, A Lim, J Shao, A Bai, X Bai, D Mantione, H Sardon, Y Y Yang, J L Hedrick

Upcycling Poly(ethylene terephthalate) Refuse to Advanced Therapeutics for the Treatment of Nosocomial and Mycobacterial Infections

Macromolecules 2019, 52, 20, 7878-7885

https://doi.org/10.1021/acs.macromol.9b01333

 

A Basterretxea, C Jehanno, D Mecerreyes, Haritz Sardon

Dual Organocatalysts Based on Ionic Mixtures of Acids and Bases: A Step Toward High temperature Polymerizations

ACS Macro Lett. 2019 8, 1055-1062

https://doi.org/10.1021/acsmacrolett.9b00481

 

I Flores, A Basterrexea, A Etxeberria, C Ocando, J F Vega, J M Salazar, H Sardon, A J  Muller

Organocatalyzed Polymerization of PET-mb-poly(oxyhexane) Copolymers and Their Self-Assembly into Double Crystalline

Macromolecules 2019, 52, 18, 6834–6848

https://doi.org/10.1021/acs.macromol.9b01110

 

A Sangroniz, J-B Zhu, X Tang, A Etxeberria, E Y.-X. Chen, H Sardon

Packaging materials with desired mechanical and barrier properties and full chemical recyclability

Nat. Comm 10, 3559 (2019)

https://doi.org/10.1038/s41467-019-11525-x

 

J Wong, A T Gong, P A Defnet, L Meabe, B Beauchamp, R M Sweet, H Sardon, C L Cobb, A Nelson

3D Printing Ionogel Auxetic Frameworks for Stretchable Sensors Advanced

Materials Technologies 2019, 4, 9, 1900452

https://doi.org/10.1002/admt.201900452

 

N Fanjul-Mosteirín, C Jehanno, F Ruipérez, H Sardon, A P Dove

Rational Study of DBU Salts for the CO2 Insertion into Epoxides for the Synthesis of Cyclic Carbonates

ACS Sustainable Chem. Eng. 2019, 7, 12 10633-10640

https://doi.org/10.1021/acssuschemeng.9b01300

 

A Basterretxea, E Gabirondo, I Flores, A Etxeberria, A Gonzalez, A J Müller, D Mecerreyes, O Coulembier and H Sardon

Isomorphic Polyoxyalkylene Copolyethers Obtained by Copolymerization of Aliphatic Diols

Macromolecules 2019,  52, 9, 3506–3515

https://doi.org/10.1021/acs.macromol.9b00469

 

C Jehanno and H Sardon

Dynamic polymer network points the way to truly recyclable plastics

Nature 568, 467-468 (2019)

https://doi.org/10.1038/d41586-019-01209-3

 

I Flores, A Etxeberria , L Irusta, I Calafel, J. F Vega, J Martínez-Salazar, H Sardon and A J Müller

PET-ran-PLA Partially Degradable Random Copolymers Prepared by Organocatalysis: Effect of Poly(l-lactic acid) Incorporation on Crystallization and Morphology ACS Sustainable

Chem. Eng. 2019, 7, 9, 8647-8659

https://doi.org/10.1021/acssuschemeng.9b00443

 

A Bossion, I Olazabal, R H Aguirresarobe, S Marina, J Martín, L Irusta, D Taton and H Sardon

Synthesis of self-healable waterborne isocyanate-free poly(hydroxyurethane)-based supramolecular networks by ionic interactions

Polym. Chem., 2019,10, 2723-2733

https://doi.org/10.1039/C9PY00439D

 

F Tabatabaee, M Khorasani, M Ebrahimi, A González, L Irusta and H Sardon

Synthesis and comprehensive study on industrially relevant flame retardant waterborne polyurethanes based on phosphorus chemistry

Prog. Org. Coat. 2019, 131, 397-406

https://doi.org/10.1016/j.porgcoat.2019.02.042

 

I Flores, A Martínez de Ilarduya, H Sardon , A J Müller and S Muñoz-Guerra

Synthesis of Aromatic–Aliphatic Polyesters by Enzymatic Ring Opening Polymerization of Cyclic Oligoesters and their Cyclodepolymerization for a Circular Economy ACS

ACS Appl. Polym. Mater. 2019, 1, 3, 321–325

https://doi.org/10.1021/acsapm.8b00265

 

A Basterretxea, E Gabirondo, C Jehanno, H Zhu, I Flores, A J Müller, A Etxeberria, D Mecerreyes, O Coulembier and H Sardon

Polyether Synthesis by Bulk Self-Condensation of Diols Catalyzed by Non-Eutectic Acid−Base Organocatalysts

ACS Sust. Chem. Eng., 2019, 7, 4, 4103–4111

https://doi.org/10.1021/acssuschemeng.8b05609

 

N Zivic, P K Kuroishi, F Dumur, D Gigmes, A P Dove, H Sardon

Recent Advances and Challenges in the Design of Organic Photoacid and Photobase Generators for Polymerizations

Angew. Chem., 2019, 58, 31, 10410-10422

https://doi.org/10.1002/anie.201810118

 

A Bossion, K V Heifferon, L Meabe, N Zivic, D Taton, J L Hedrick, T E Long, H Sardon*

Opportunities for organocatalysis in polymer synthesis via step-growth methods

Prog Polym Sci 2019, 90, 164-210

https://doi.org/10.1016/j.progpolymsci.2018.11.003

 

C Jehanno, M M Pérez-Madrigal, J Demarteau, H Sardon and A P. Dove

Organocatalysis for depolymerisation

Polym. Chem., 2019,10, 172-186

https://doi.org/10.1039/C8PY01284A

2018

E Verde-Sesto, N Goujon, H Sardon, P Ruiz, T Vu Huynh, F Elizalde, D Mecerreyes, M Forsyth, L A O´Dell

DNP NMR Studies of Crystalline Polymer Domains by Copolymerization with Nitroxide Radical Monomers

Macromolecules, 2018, 51 (20), 8046-8053

https://doi.org/10.1021/acs.macromol.8b01665

 

H Sardon and A P Dove

Plastic recycling with a difference

Science 2018, Vol. 360, Issue 6387, 380-381

https://doi.org.10.1126/science.aat4997

 

A Bossion, R H Aguirresarobe, L Irusta, D Taton, H Cramail, E Grau, D Mecerreyes, C Su, G Liu, A J Müller, H Sardon

Unexpected Synthesis of Segmented Poly(hydroxyurea-urethane)s from Dicyclic Carbonates and Diamines by Organocatalysis

Macromolecules, 2018, 51 (15), 5556-5566

https://doi.org/10.1021/acs.macromol.8b00731

 

A Y Yuen, A Bossion, A Veloso, D Mecerreyes, J L Hedrick, A P Dove and H Sardon

Efficient polymerization and post-modification of N-substituted eight-membered cyclic carbonates containing allyl groups

Polym. Chem., 2018,9, 2458-2467

https://doi.org/10.1039/C8PY00231B

 

I Flores, J Demarteau, A J Muller, A Etxeberria, L Irusta, F Bergman, C Koning, H Sardon

Screening of Different Organocatalysts for the Sustainable Synthesis of PET

Eur Polym J. 2018,104, 170-176

https://doi.org/10.1016/j.eurpolymj.2018.04.040

 

N Sadaba, M Salsamendi, N Casado, E Zuza, J Muñoz, J-R Sarasua, D Mecerreyes, D Mantione, C Detrembleur, H Sardon

Catechol End-Functionalized Polylactide by Organocatalyzed Ring-Opening Polymerization

Polymers 2018, 10(2), 155

https://doi.org/10.3390/polym10020155

 

L Meabe, T Vu Huynh, N Lago, H Sardon, C M Li, L A O’Dell, M Armand, M Forsyth, D Mecerreyes

Poly(ethylene oxide carbonates) solid polymer electrolytes for lithium batteries

Electrochimica Acta 2018, 367-375

https://doi.org/10.1016/j.electacta.2018.01.101

 

A Y Yuen, L Porcarelli, R H Aguirresarobe, A Sanchez-Sanche, I del Agua, U Ismailov, G G Malliaras, D Mecerreyes, E Ismailova, H Sardon

Biodegradable Polycarbonate Iongels for Electrophysiology Measurements

Polymers 2018, 10(9), 989

https://doi.org/10.3390/polym10090989

 

C Jehanno, I Flores, A P Dove, A J Müller, F Ruipérez, H Sardon

Organocatalaysed depolymerisation of PET in a fully sustainable cycle using thermally stable protic ionic salt

Green Chem. 2018, 20, 1205-1212

https://doi.org/10.1039/C7GC03396F

2017

A Y Yuen, E Lopez-Martinez, E Gomez-Bengoa, A L Cortajarena, R H Aguirresarobe, A Bossion, D Mecerreyes, J L Hedrick, Y Yan Yang, H Sardon

Preparation of Biodegradable Cationic Polycarbonates and Hydrogels through the Direct Polymerization of Quaternized Cyclic Carbonates

ACS Biomater. Sci. Eng  2017, 3, 8, 1567–1575

https://doi.org/10.1021/acsbiomaterials.7b00335

 

L Meabe, H Sardon, D Mecerreyes

Hydrolytically degradable poly(ethylene glycol) based polycarbonates by organocatalyzed condensation

Eur. Polym. J. 2017, 95, 737-745

https://doi.org/10.1016/j.eurpolymj.2017.06.046

 

E Udabe, M Isik, H Sardon, L Irusta, M Salsamendi, Z Sun, Z Zheng, F Yan, D Mecerreyes

Antimicrobial polyurethane foams having cationic ammonium groups

J. Appl. polym Sci. 2017, 134, 45, 45473

https://doi.org/10.1002/app.45473

 

D Mantione, N Casado, A Sanchez-sanchez, H Sardon, D Mecerreyes

Easy-to-make carboxylic acid dioxythiophene monomer (ProDOT-COOH) and functional conductive polymers

Polym. Chem. 2017, 55, 17, 2721-2724

https://doi.org/10.1002/pola.28690

 

L I Roncoa, A Basterretxea, D Mantione, R H Aguirresarobe, R J Minari, L M Gugliotta, D Mecerreyes, H Sardon

Temperature responsive PEG-based polyurethanes “à la carte”

Polymer 2017, 122, 117-124

https://doi.org/10.1016/j.polymer.2017.06.043

 

X An, R H Aguirresarobe, L Irusta,  F Ruipérez,  J M Matxain,  X Pan,  N Aramburu,  D Mecerreyes,  H Sardon,  Jian Zhu

Aromatic diselenide crosslinkers to enhance the reprocessability and self-healing of polyurethane thermosets

Polym. Chem. 2017, 8, 3641-3646

https://doi.org/10.1039/C7PY00448F

 

A Basterretxea, E Gabirondo, A Sanchez-Sanchez, A Etxeberria, O Coulembier, D Mecerreyes, H Sardon

Synthesis and characterization of poly (e-caprolactam-co-lactide) polyesteramides using Brønsted acid or Brønsted base organocatalyst

Eur. Polym. J 2017, 95, 650-659

https://doi.org/10.1016/j.eurpolymj.2017.05.023

 

D Mantione, I del Agua, W Schaafsma, M ElMahmoudy, I Uguz, A Sanchez-Sanchez, H Sardón, B Castro, G G Malliaras, David Mecerreyes

Low temperature cross-linking of PEDOT:PSS films using divinylsulfone

ACS applied and interfaces 2017, 9, 21, 18254–18262

https://doi.org/10.1021/acsami.7b02296

 

J P K Tan, D J Coady, H Sardon, A Yuen, S Venkataraman, A C Engler, R Ono, Y Y Yang, J L Hedrick

Broad spectrum macromolecular antimicrobials with biofilm disruption capability and in vivo efficacy

Adv. Health. Mater. 2017, 6, 16, 1601420

https://doi.org/10.1002/adhm.201601420

 

L Porcarelli, K Manojkumar, H Sardon, O Llorente, A S Shaplove, K Vijayakrishna, C Gerbaldi, D Mecerreyes

Single Ion Conducting Polymer Electrolytes Based on Versatile Polyurethanes

Electrochimica Acta 241 (2017) 526-534

https://doi.org/10.1016/j.electacta.2017.04.132

 

S Garmendia, D Mantione,  S Alonso-de Castro,  C Jehanno,  L Lezama,  J L Hedrick,  D Mecerreyes,  L Salassa  and  Ha Sardon

Polyurethane based organic macromolecular contrast agents (PU-ORCAs) for magnetic resonance imaging

Polym. Chem. 2017, 8, 2693-2701

https://doi.org/10.1039/C7PY00166E

 

Le eabe, N Lago, L Rubatat, C Li, A J Müller, H Sardon, M Armand, D Mecerreyes

Polycondensation as a Versatile Synthetic Route to Aliphatic Polycarbonates for Solid Polymer Electrolytes

Electrochimica Acta 237 (2017) 259–266

https://doi.org/10.1016/j.electacta.2017.03.217

 

Sofia M. Morozova, Alexander S. Shaplov, Elena I. Lozinskaya, Petr S. Vlasov, Haritz Sardon, David Mecerreyes and Yakov S. Vygodskii

Poly(ionic liquid)-based polyurethanes having imidazolium, ammonium, morpholinium, or pyrrolidonium cations

High Performance Polymers

https://doi.org/10.1177/0954008317701551

 

A Sanchez-Sanchez, I Rivilla, M Agirre, A Basterretxea, A Etxeberria, A Veloso, H Sardon, D Mecerreyes, Fernando P. Cossio

Enantioselective Ring-Opening Polymerization of rac-Lactide Dictated by Densely Substituted Aminoacids

J. Am. Chem. Soc., 2017, 139 (13), pp 4805–4814.

https://doi.org/10.1021/jacs.6b13080

 

S Morozova, A Shaplov, E Lozinskaya, D Mecerreyes, H Sardon, S Zulfiqar, F Suárez-García, Y Vygodskii

Ionic polyurethanes as new family of poly(ionic liquid)s for efficient CO2 capture

Macromolecules, 2017, 50 (7), pp 2814–2824

https://doi.org/10.1021/acs.macromol.6b02812

 

J M W Chan, R J Wojtecki, H Sardon, A L Z Lee, C E Smith, A Shkumatov, S Gao, H Kong, Y Y Yang, J L Hedrick

Self-Assembled, Biodegradable Magnetic Resonance Imaging Agents: Organic Radical-Functionalized Diblock Copolymers

ACS Macro Lett., 2017, 6, pp 176–180

https://doi.org/10.1021/acsmacrolett.6b00924

 

A Bossion, G O Jones, D Taton, D Mecerreyes, J L Hedrick, Z Y Ong, Y Y Yang, H Sardon

Non-Isocyanate Polyurethane Soft Nanoparticles Obtained by Surfactant-Assisted Interfacial Polymerization

Langmuir, 2017, 33 (8), pp 1959–1968

https://doi.org/10.1021/acs.langmuir.6b04242

 

H Daemi, M Barikani, H Sardon

Transition-metal-free synthesis of supramolecular ionic alginate-based polyurethanes

Carbohydr. Polym. 2017, 157, 1949-1954

https://doi.org/10.1016/j.carbpol.2016.11.086

 

M Isik, M Agirre, J Zarate, G Puras, D Mecerreyes, H Sardon, J L Pedraz

Amine Containing Cationic Methacrylate Copolymers as Efficient Gene Delivery Vehicles to Retinal Epithelial Cells

Polym. Sci., Part A 2017, 2, 280-287

https://doi.org/10.1002/pola.28376

 

M Ribeiro, M P Ferraz, F J Monteiro, M H Fernandes, M M Beppu, D Mantione, Haritz Sardon

Antibacterial silk fibroin/nanohydroxyapatite hydrogels with silver and gold nanoparticles for bone regeneration Nanomedicine

Nanomedicine 2017, 13(1,) 231-239

https://doi.org/10.1016/j.nano.2016.08.026

2016

A Basterretxea, Y Haga, A Sanchez-Sanchez, M Isik, L Irusta, M Tanaka, K Fukushima, Haritz Sardon

Biocompatibility and hemocompatibility evaluation of polyether urethanes synthesized using DBU organocatalyst

Eur. Polym. J. 2016, 84, 750-758

https://doi.org/10.1016/j.eurpolymj.2016.08.008

 

M Isik, J P K Tan, R J Ono, A Sanchez-Sanchez, D Mecerreyes, Y Y Yang, J L Hedrick, H Sardon

Tuning the antimicrobial properties of biodegradable polycarbonates by simple anion-exchange reactions

Macro. Biosci. 2016, 16, 1360-1367

https://doi.org/10.1002/mabi.201600090

 

J Fernández, H Amestoy, H Sardon, M Aguirre, A Larrañaga Varga, Jose-Ramon Sarasua

Effect of the molecular weight on the mechanical properties an crystallization of poly(ethylene brassylate) homopolymers

J Mech. Behav. Biomed. Mater. 2016, 64, 209-219

https://doi.org/10.1016/j.jmbbm.2016.07.031

 

J S Desport, D Mantione, M Moreno, H Sardón, M J Barandiaran, D Mecerreyes

Synthesis of three different galactose-based methacrylate monomers for the production of sugar-based polymers

Carbohydrate research 2016, 232, 50-54

https://doi.org/10.1016/j.carres.2016.06.008

 

D Mantione, I del Agua, W Schaafsma, J Diez-Garcia, B Castro, H Sardon, D Mecerreyes

Poly(3,4-ethylenedioxythiophene):GlycosAminGlycan (PEDOT:GAG) aqueous Dispersions: Towards Electrically Conductive Bioactive Materials for Neural Interfaces

Macro. Biosci 2016, 16, 1227-1238

https://doi.org/10.1002/mabi.201600059

 

A Sanchez-Sanchez, A Basterretxea, D Mantione, A Etxeberria, C Elizetxea, A de la Calle, S García-Arrieta, H Sardon, D Mecerreyes

Organo-mediated bulk polymerization of ε-Caprolactam and its Copolymerization with ε-Caprolactone using sulfonic acids

J. Polym. Sci., Part A 2016, 54, 2394-2402

https://doi.org/10.1002/pola.28114

 

J M W Chan, J P K Tan, A C Engler, X Ke, S Gao, C Yang, H Sardon, Y Y Yang, J L Hedrick

Anticancer Drug Loading of Degradable Polymeric Mixed Micelles via a Biomimetic Mechanism

Macromolecules, 2016, 49 (6), 20132021

https://doi.org/10.1021/acs.macromol.5b02784

 

M Isik, F Ruiperez, H Sardon, A Gonzalez, S Zulfiqar, D Mecerreyes

Innovative Poly(ionic liquid)s by the Polymerization of Deep Eutectic Monomers

Macro. Rapid Comm., 2016, 37, 11351142

https://doi.org/10.1002/marc.201600026

 

A Yuen, A Bossion, E Gómez-Bengoa, F Ruipérez, M Isik, J L Hedrick, D Mecerreyes, Y Y Yang, H Sardon

Room temperature synthesis of isocyanate free poly(hydroxyurethanes) using highly reactive N-substituted 8-membered cyclic carbonates.

Polym. Chem. 2016, 7, 2105-2111

https://doi.org/10.1039/C6PY00264A

 

H Daemi, S Rajabi-Zeleti, H Sardon, M Barikani, A Khademhosseini, H Baharvand

A Robust Super-Tough Biodegradable Elastomer Engineered by Supramolecular Ionic Interactions.

Biomaterials 2016, 84, 54-63

https://doi.org/10.1016/j.biomaterials.2016.01.025

 

W N Ottou, H Sardon, D Mecerreyes, J Vignolle, D Taton

Update and challenges in organo-mediated polymerization reactions

Prog. Polym. Sci. 2016, 56, 64115

https://doi.org/10.1016/j.progpolymsci.2015.12.001

 

N Casado, G Hernández, H Sardon, D Mecerreyes

Current Trends in Redox Polymers for Energy and Nanomedicine

Prog. Polym. Sci. 2016, 52, 107-135

https://doi.org/10.1016/j.progpolymsci.2015.08.003

 

2015

S Venkataraman, V W L Ng, D J Coady, H W Horn, G O Jones, T S Fung, H Sardon, R M Waymouth, J L Hedrick, Y Y Yang

A Simple and Facile Approach to Functional Eight-Membered Aliphatic Cyclic Carbonates and Their Organo-catalytic Polymerization.

J. Am. Chem. Soc.2015, 137, 13851-13860

https://doi.org/10.1021/jacs.5b06355

 

M Isik, T Lonjaret, H Sardon, R Marcilla, T Herve, G G Malliaras, E Ismailova, D Mecerreyes

Cholinium Based Ion Gels as Electrolytes for Long-Term Cutaneous Recordings.

Mater. Chem. C, 2015, 3, 8942-8948

https://doi.org/10.1039/C5TC01888A

 

H Sardon, J P K Tan, J M W Chan, D Mantione, D Mecerreyes, J L Hedrick, Y Y Yang

Thermoresponsive Random Poly(ether urethane) based Nanoparticles with Tailorable LCSTs for Anticancer Drug Delivery.

Macromol. Rapid Comm. 2015, 36 (19), 1761-1767

https://doi.org/10.1002/marc.201500247

 

H Sardon, A Pascual, D Mecerreyes, D Taton, H Cramail, J L Hedrick

Synthesis of Polyurethanes using Organocatalysis: A Perspective

Macromolecules 2015, 48, 31533165

https://doi.org/10.1021/acs.macromol.5b00384

 

A Pascual, J P K Tan, A Yuen, J M W Chan, D J Coady, D Mecerreyes, J L Hedrick, Y Y Yang, H Sardon

Broad-Spectrum Antimicrobial Polycarbonate Hydrogels with Fast Degradability

Biomacromolecules 2015, 16 (4), 1169–1178

https://doi.org/10.1021/bm501836z

 

Q Xu, H Sardon, J M W Chan, J L Hedrick, Y Y Yang

Polyurethane-coated silica particles with broad-spectrum antibacterial properties

Polym. Chem. 2015,6, 20112022

https://doi.org/10.1039/C4PY01455C

 

H Sardon, A González, M J Fernández-Berridi, L. Irusta

Oxygen Barrier Properties of Waterborne Polyurethane/Silica Hybrids

J. Macromol. Sci. B. 2015, 54, 711-721

https://doi.org/10.1080/00222348.2015.1035613

 

J M W Chan, X Zhang, M K Brennan, H Sardon, A C Engler, C H Fox, C W Frank, R M Waymouth, J L Hedrick

Organocatalytic Ring-Opening Polymerization of Trimethylene Carbonate to Yield a Biodegradable Polycarbonate

J. Chem. Educ., 2015, 92 (4), 708713

https://doi.org/10.1021/ed500595k

 

A Pascual, H Sardón, F Ruipérez, R Gracia, P Sudam, A Veloso, D Mecerreyes

Experimental and Computational Studies of Ring Opening Polymerization of Ethylene Brassylate Macrolactone and Copolymerization with ε-caprolactone and TBD-guanidine Organic Catalyst

J. Polym. Sci., Part A: Polym. Chem. 2015, 53 (4), 552-561

https://doi.org/10.1002/pola.27473

 

2014

V W L Ng, et al.

Antimicrobial hydrogels: a new weapon in the arsenal against multidrug-resistant infections

Adv. Drug Delivery Rev. 2014, 78, 46-62

https://doi.org/10.1016/j.addr.2014.10.028

 

M Isik, et al.

New amphiphilic block copolymers from lactic acid and cholinium building units

RSC Adv. 2014, 4, 53407-53410

https://doi.org/10.1039/C4RA10063H

 

A Pascual, et al.

Organocatalyzed Synthesis of Aliphatic Polyesters from Ethylene Brassylate: a Cheap and Renewable Macrolactone

ACS Macro Lett. 2014, 3 (9), 849-853

https://doi.org/10.1021/mz500401u

 

M Isik, et al.

Ionic Liquids and Cellulose: Dissolution, Chemical Modification and Preparation of New Celullosic Materials

Int. J. Mol. Sci. 2014, 15, 11922-11940

https://doi.org/10.3390/ijms150711922

 

J M W Chan, et al.

Chemically Modifiable N-Heterocycle-functionalized Polycarbonates as a Platform for Diverse Smart Biomimetic Nanomaterials

Chem. Sci. 2014, 5, 3294-3300

https://doi.org/10.1039/C4SC00789A

 

H Sardon, et al.

Polymer/silica nanohybrids by means of tetraethoxysilane sol–gel condensation onto waterborne polyurethane particles.

Prog. Org. Coat. 2014, 77, 1436–1442

http://dx.doi.org/10.1016/j.porgcoat.2014.04.032 

 

H Sardon, et al.

Highly Tunable Polyurethanes: Organocatalyzed Polyaddition and Subsequent Post-polymerization Modification of Pentafluorophenyl Ester Sidechains.

Polym. Chem. 2014, 5, 3547-3550

https://doi.org/10.1039/C4PY00262H

 

D P Sanders, et al.

Synthesis of functionalized cyclic carbonate monomers using a versatile pentafluorophenyl carbonate intermediate.

Polym. Chem. 2014, 5(2), 327-329

https://doi.org/10.1039/C3PY01128C

 

2013

H Sardon, et al.

Organic Acid-Catalyzed Polyurethane Formation via a Dual-Activated Mechanism: Unexpected Preference of NActivation overOActivation of Isocyanates.

J. Am. Chem. Soc. 2013, 135, 1623516241

https://dx.doi.org/10.1021/ja408641g

 

J M W Chan, et al.

Tetra-n-butylammonium Fluoride as an Efficient Transesterification Catalyst for the Functionalization of Cyclic Carbonates and Aliphatic Polycarbonates.

ACS Macro Lett., 2013, 2(10) 860–864

https://doi.org/10.1021/mz400334j

 

A Pascual, et al.

Organocatálisis: hacia una nueva generación de catalizadores para la síntesis de polímeros

Anales de Química 2013, 109(3), 173–181

 

H Sardon, et al.

Waterborne hybrid polyurethane coatings functionalized with (3-aminopropyl)triethoxysilane: Adhesion properties.

Prog. Org. Coat. 2013, 76, 1230–1235

https://doi.org/10.1016/j.porgcoat.2013.03.025

 

H Sardon, et al.

Homogeneous isocyanate-and catalyst-free synthesis of polyurethanes in aqueous media.

Green Chem., 2013, 15, (5), 1121-1126

https://doi.org/10.1039/C3GC40319J

 

D J Coady, et al.

Polymerizing Base Sensitive Cyclic Carbonates Using Acid Catalysis

ACS Macro Lett.2013,2(4),306-312

https://doi.org/10.1021/mz3006523

 

A C Engler, et al.

Accessing New Materials through Polymerization and Modification of a Polycarbonate with a Pendant Activated Ester.

Macromolecules 2013, 46 (4),1283-1290

https://doi.org/10.1021/ma4001258