2023
Most recent scientific publications
Maria Rosaria Caputo, Mercedes Fernández, Robert Aguirresarobe, Adriana Kovalcik, Haritz Sardon, María Virginia Candal, Alejandro J Müller
Influence of FFF Process Conditions on the Thermal, Mechanical, and Rheological Properties of Poly (hydroxybutyrate-co-hydroxy Hexanoate)
Polymers 2023, 15(8), 1817.


L. Polo Fonseca, A. Duval, E. Luna, M. Ximenis, S. De Meester, L. Avérous, H. Sardon
Reducing the carbon footprint of polyurethanes by chemical and biological depolymerization: Fact or fiction?
Current Opinion in Green and Sustainable Chemistry 2023, 41, 100802


Ion Olazabal, Emelin J Luna Barrios, Steven De Meester, Coralie Jehanno, Haritz Sardon
Upcycling of BPA-PC into trimethylene carbonate by solvent assisted organocatalysed depolymerisation
Polymer Chemistry 2023, Advance article.

I Olazabal, A Gonzalez, S Vallejos, I Rivilla, C Jehanno, H Sardon
Upgrading Polyurethanes into Functional Ureas through the Asymmetric Chemical Deconstruction of Carbamates
ACS SUSTAIN CHEM ENG. 2023, 11 (1) 332-342.

M Aguirre, N Ballard, E Gonzalez, S Hamzehlou, H Sardon, M Calderon, M Paulis, R Tomovska, D Dupin, R Bean, T Long, JR Leiza, J Asua
Polymer Colloids: Current Challenges, Emerging Applications, and New Developments
MACROMOLECULES. 2023, – (-) -.

2022
A Gomez-Lopez, B Grignard, I Calvo, C Detrembleur, H Sardon
Accelerating the Curing of Hybrid Poly(Hydroxy Urethane)-Epox y Adhesives by the Thiol-Epoxy Chemistry
ACS Appl. Polym. Mater. 2022, 4 (12), 8786–8794

A Dove, M Hong, J Lamb, H Sardon
Treating the plastic problem: From renewable feedstocks and degradability to recycling
Journal of Polymer Science 2022, 60 (24), 3253-3255


H Sardon, T Long, H Le Ferrand
Sustainable Additive Manufacturing of Plastics
ACS Sustainable Chemistry & Engineering 2022, 10 (6), 1983-1985


A Sangroniz, JB Zhu, A Etxeberria, EYX Chen, H Sardon
Modulating the crystallinity of a circular plastic towards packaging material with outstanding barrier properties
Macromolecular Rapid Communications 2022, 2200008

C Jehanno, JW Alty, M Roosen, S De Meester, AP Dove, E Chen, FA Leibfarth, H Sardon
Critical advances and future opportunities in upcycling commodity polymers.
Nature. 2022, 603, p. 803-814.

MR Caputo, X Tang, AH Westlie, H Sardon, EY-X Chen, AJ Müller.
Effect of Chain Stereoconfiguration on Poly(3-hydroxybutyrate) Crystallization Kinetics.
Biomacromolecules. 2022, 23 (9), p. 3847-3859.

A Dominguez, M Criado, E Gabirondo, H Lasa, JL Olmedo, N Casado, N Alegret, AJ Müller, H Sardon, A Vallejo, D Mecerreyes.
Electroactive 3D printable poly(3,4-ethylenedioxythiophene)-graft-poly(epsilon-caprolactone) copolymers as scaffolds for muscle cell alignment.
Polym. Chem. 2022, 13 (1), p. 109-120.


A Gomez, N Ayensa, B Grignard, L Irusta, I Calvo, AJ Müller, C Detrembleur, H Sardon.
Enhanced and Reusable Poly(hydroxy urethane)-Based Low Temperature Hot-Melt Adhesives.
Acs Polymers Au. 2022, 2 (3), p. 194-207

S Atia, K Zeggagh, S Hadjout, A Etxeberria, Z Benabdelghani.
Enhancement of semiconducting and thermomechanical properties of materials based on polyaniline and polyvinylpyrrolidone.
J. Polym. Res. 2022, 29 (4), 138.

I Olazabal, N Goujon, D Mantione, M Alvarez, C Jehanno, D Mecerreyes, H Sardon.
From plastic waste to new materials for energy storage.
Polym. Chem. 2022, 13(29), p. 4222-4229.

A Hernández, HA Houck, F Elizalde, M Guerre, H Sardon, FE Du.
Internal catalysis on the opposite side of the fence in non-isocyanate polyurethane covalent adaptable networks.
Eur Polym J. 2022, 168, 111100.


A Sangroniz, L Sangroniz, S Hamzehlou, N Aranburu, H Sardon, JR Sarasua, M Iriarte, JR Leiza, A Etxeberria.
Lactide-valerolactone copolymers for packaging applications.
Polym. 2022, 14 (1), p. 52.

G Damonte, L Maddalena, A Fina, D Cavallo, AJ Müller, MR Caputo, A Mariani, O Monticelli.
On novel hydrogels based on poly(2-hydroxyethyl acrylate) and polycaprolactone with improved mechanical properties prepared by frontal polymerization.
Eur Polym J. 2022, 171, 111226.

F Elizalde, J Amici, S Trano, G Vozzolo, R Aguirresarobe, D Versaci, S Bodoardo, D Mecerreyes, H Sardon, F Bella.
Self-healable dynamic poly(urea-urethane) gel electrolyte for lithium batteries.
J. Mater. Chem. A. 2022, 10 (23), p. 12588-12596.

M Valle, M Ximenis, X Lopez de Pariza, JMW Chan, H Sardon.
Spotting Trends in Organocatalyzed and Other Organomediated (De)polymerizations and Polymer Functionalizations.
Angew. Chem. Int. Ed. 2022, 61 (36), e202203043.


SE Fenni, MR Caputo, AJ Müller, D Cavallo.
Surface Roughness Enhances Self-Nucleation of High-Density Polyethylene Droplets Dispersed within Immiscible Blends.
Macromolecules. 2022, 55 (4), p. 1412-1423.

DE Fagnani, C Jehanno, H Sardon, AJ McNeil.
Sustainable Green Polymerizations and End-of-Life Treatment of Polymers.
Macromol. Rapid Commun. 2022, 43(13), 2200446.

XL de Pariza, T Erdmann, PL Arrechea, L Perez, C Dausse, NH Park, JL Hedrick, H Sardon.
Synthesis of Tailored Segmented Polyurethanes Utilizing Continuous-Flow Reactors and Real-Time Process Monitoring.
Chem. Mater. 2021, 33 (20), p. 7986-7993.


I Flores, RA Perez, E Gabirondo, MR Caputo, GM Liu, DJ Wang, H Sardon, AJ Müller.
Unexpected Structural Properties in the Saturation Region of the Odd-Even Effects in Aliphatic Polyethers: Influence of Crystallization Conditions.
Macromolecules. 2022, 55. (2), p. 584-594.

F Siragusa, J Demarteau, T Habets, I Olazabal, K Robeyns, G Evano, R Mereau, T Tassaing, B Grignard, H Sardon, C Detrembleur.
Unifying Step-Growth Polymerization and On-Demand Cascade Ring-Closure Depolymerization via Polymer Skeletal Editing.
Macromolecules. 2022, 55. (11), p. 4637-4646.

2021
A Dominguez, E Gabirondo, N Alegret, CM De León, R Hernandez, A Vallejo, M Prato, D Mecerreyes.
3D Printable Conducting and Biocompatible PEDOT-graft-PLA Copolymers by Direct Ink Writing.
Macromol. Rapid Commun. 2021, 42 (12), 2100100.

A Gallastegui, E Gabirondo, F Elizalde, N Aranburu, D Mecerreyes, H Sardon.
Chemically recyclable glycerol-biobased polyether thermosets.
Eur Polym J. 2021, 143, 110174.

RA Perez, L Meabe, G Liu, H Sardon, Y Zhao, D Wang, AJ Müller.
Even-Odd Effect in Aliphatic Polycarbonates with Different Chain Lengths: from Poly (Hexamethylene Carbonate) to Poly (Dodecamethylene Carbonate).
Macromolecules. 2021, 54 (1), p. 259-271.

EM Niemczyk, A Gomez, JRN Haler, G Frache, H Sardon, R Quintana.
Insights on the atmospheric-pressure plasma-induced free-radical polymerization of allyl ether cyclic carbonate liquid layers.
Polym. 2021, 13 (17), 2856.

E Carmeli, SE Fenni, MR Caputo, AJ Müller, D Tranchida, D Cavallo.
Surface Nucleation of Dispersed Polyethylene Droplets in Immiscible Blends Revealed by Polypropylene Matrix Self-Nucleation.
Macromolecules. 2021, 54 (19), p. 9100-9112.

A Gomez, F Elizalde, I Calvo, H Sardon.
Trends in non-isocyanate polyurethane (NIPU) development.
Chem. Commun. 2021, 57 (92), p. 12254-12265.

M Safari, I Otaegi, N Aramburu, G Guerrica, AM De Ilarduya, H Sardon, AJ Müller.
Synthesis, structure, crystallization and mechanical properties of isodimorphic PBS-ran-PCL copolyesters
Polym. 2021, 13 (14), 2263.

R A Pérez-Camargo, G Liu, L Meabe, Y Zhao, H Sardon, A J Müller, D Wang
Using Successive Self-Nucleation and Annealing to Detect the Solid–Solid Transitions in Poly (hexamethylene carbonate) and Poly (octamethylene carbonate)
Macromolecules 2021, 54 (20), p. 9670-9680.

N Fanjul-Mosteirín, R Aguirresarobe, N Sadaba, A Larrañaga, E Marin, J Martin, N Ramos-Gomez, M C Arno, H Sardon, A P Dove
Crystallization-Induced Gelling as a Method to 4D Print Low-Water-Content Non-isocyanate Polyurethane Hydrogels
Chemistry of materials 2021, 33 (18), 7194–7202

H Sardon, D Mecerreyes, A Basterretxea, L Avérous, C Jehanno
From Lab to Market: Current Strategies for the Production of Biobased Polyols
ACS Sustainable Chemistry & Engineering 2021, 9 (32), 10664-10677

R A Pérez-Camargo, G Liu, L Meabe, Y Zhao, H Sardon, D Wang, A J Müller
Solid–Solid Crystal Transitions (δ to α) in Poly(hexamethylene carbonate) and Poly(octamethylene carbonate)
Macromolecules 2021, 54 (15), 7258-7268.

A Gomez-Lopez, S Panchireddy, B Grignard, I Calvo, C Jerome, C Detrembleur, H Sardon
Poly (hydroxyurethane) Adhesives and Coatings: State-of-the-Art and Future Directions
ACS Sustainable Chem. Eng. 2021, 9(29), 9541–9562

M Safari, I Otaegi, N Aramburu, G Guerrica-Echevarria, A Martínez Martínez de Ilarduya, H Sardon, A J Müller
Synthesis, Structure, Crystallization and Mechanical Properties of Isodimorphic PBS-ran-PCL Copolyesters
Polymers 2021, 13(14), 2263

X Lopez de Pariza, E Cordero Jara, N Zivic, F Ruipérez, T E Long, H Sardon
Novel imino- and aryl-sulfonate based photoacid generators for the cationic ring-opening polymerization of ε-caprolactone
Polym. Chem., 2021, 12, 4035-4042

J L Olmedo-Martínez, M Pastorio, E Gabirondo, A Lorenzetti, H Sardon, D Mecerreyes, A J Müller
Polyether Single and Double Crystalline Blends and the Effect of Lithium Salt on Their Crystallinity and Ionic Conductivity
Polymers 2021, 13(13), 2097

O Llorente, A Agirre, I Calvo, M Olaso, R Tomovska, H Sardon
Exploring the advantages of oxygen-tolerant thiol-ene polymerization over conventional acrylate free radical photopolymerization processes for pressure-sensitive adhesives
Polym J 2021, 53, 1195–1204.


A Basterretxea, E Gabirondo, C Jehanno, H Zhu, O Coulembier, D Mecerreyes, H Sardon
Stereoretention in the Bulk ROP of l-Lactide Guided by a Thermally Stable Organocatalyst
Macromolecules 2021, 54, 13, 6214–6225

S Marina, A D Scaccabarozzi, E Gutierrez‐Fernandez, E Solano, A Khirbat, L Ciammaruchi, A Iturrospe, A Balzer, L Yu, E Gabirondo, X Monnier, H Sardon, T D Anthopoulos, M Caironi, M Campoy‐Quiles, C Müller, D Cangialosi, N Stingelin, Jaime Martin
Polymorphism in Non‐Fullerene Acceptors Based on Indacenodithienothiophene
Advanced Functional Materials 2021, 31, 29, 2103784

E Sanchez-Rexach, P T Smith, A Gomez-Lopez, M Fernandez, A L Cortajarena, H Sardon, A Nelson
3D-Printed Bioplastics with Shape-Memory Behavior Based on Native Bovine Serum Albumin
ACS Appl. Mater. Interfaces 2021, 13, 16, 19193–19199


C Jehanno, J Demarteau, D Mantione, M C Arno, F Ruiperez, J L Hendrick, A P Dove, H Sardon
Selective Chemical Upcycling of Mixed Plastics Guided by a Thermally Stable Organocatalyst
Angewandte Chemie International Edition 60 (12), 6710-6717

M Riechers, L Fanini, A Apicella, C B Galván, E Blondel, B Espiña, S Kefer, …
Plastics in our ocean as a transdisciplinary challenge
Marine Pollution Bulletin 164, 112051


A Gomez-Lopez, B Grignard, I Calvo, C Detrembleur, H Sardon
Synergetic Effect of Dopamine and Alkoxysilanes in Sustainable Non-Isocyanate Polyurethane Adhesives
Macromolecular Rapid Communications 42 (3), 2000538

R H Aguirresarobe, S Nevejans, B Reck, L Irusta, H Sardon, J M Asua, N Ballard
Healable and self-healing polyurethanes using dynamic chemistry
Progress in Polymer Science 114, 101362

A Gallastegui, E Gabirondo, F Elizalde, N Aranburu, D Mecerreyes, H Sardon
Chemically recyclable glycerol-biobased polyether thermosets
European Polymer Journal 143, 110174


V Montagna, J Takahashi, M Y Tsai, T Ota, N Zivic, S Kawaguchi, T Kato, M Tanaka, H Sardon, K Fukushima
Methoxy-Functionalized Glycerol-Based Aliphatic Polycarbonate: Organocatalytic Synthesis, Blood Compatibility, and Hydrolytic Property
ACS Biomaterials Science & Engineering 7 (2), 472-481


X Monnier, S Marina, X Lopez de Pariza, H Sardón, J Martin, D Cangialosi
Physical Aging Behavior of a Glassy Polyether
Polymers 13 (6), 954

E Gabirondo, B Melendez-Rodriguez, C Arnal, J M Lagaron, A Martínez de Ilarduya, H Sardon, S Torres-Giner
Organocatalyzed closed-loop chemical recycling of thermo-compressed films of poly (ethylene furanoate)
Polymer Chemistry 12 (10), 1571-1580


2020
K O’Harra, N Sadaba, M Irigoyen, F Ruipérez, R Aguirresarobe, H Sardon, J Bara
Nearly Perfect 3D Structures Obtained by Assembly of Printed Parts of Polyamide Ionene Self-Healing Elastomer
ACS Applied Polymer Materials 2020, 2, 11, 4352–4359
S M Morozova, E I Lozinskaya, H Sardon, F Suárez-García, P S.Vlasov, R Vaudemont, Y S Vygodskii, A S Shaplov
Ionic Polyureas—A Novel Subclass of Poly(Ionic Liquid)s for CO2 Capture
Membranes 2020, 10, 240
E Sanchez-Rexach, T G Johnston, C Jehanno, H Sardon, A Nelson
Sustainable Materials and Chemical Processes for Additive Manufacturing
Chem. Mater. 2020, 32, 17, 7105–7119
From plastic waste to polymer electrolytes for batteries through chemical upcycling of polycarbonate
J Mater Chem A 2020, 8, 13921-13926
J Demarteau, I Olazabal, C Jehanno, H Sardon
Aminolytic upcycling of poly(ethylene terephthalate) wastes using a thermally-stable organocatalyst
Polymer Chem 2020, 11, 4875-4882
L Sangroniz, A Sangroniz, L Meabe, A Basterretxea, H Sardon, D Cavallo, A J Müller
Chemical Structure Drives Memory Effects in the Crystallization of Homopolymers
Macromolecules 2020, 53, 12, 4874–4881
A Basterretxea, X Lopez de Pariza, E Gabirondo, S Marina, J Martin, A Etxeberria, D Mecerreyes, H Sardon
Synthesis and Characterization of Fully Biobased Copolyether Polyols
Ind. Eng. Chem. Res. 2020, 59, 23, 10746–10753
J Demarteau, K E O’Harra, J E Bara, H Sardon
Valorization of Plastic Wastes for the Synthesis of Imidazolium Based Self‐Supported Elastomeric Ionenes
ChemSusChem 2020, 13, 12, 3122-3126
J Huang, C Jehanno, J C Worch, F Ruipérez, H Sardon, A P Dove, O Coulembier
Selective Organocatalytic Preparation of Trimethylene Carbonate from Oxetane and Carbon Dioxide
ACS Catal. 2020, 10, 10, 5399–5404
A Gomez-Lopez, B Grignard, I Calvo, C Detrembleur, H Sardon
Monocomponent Non-isocyanate Polyurethane Adhesives Based on a Sol–Gel Process
ACS Appl. Polym. Mater. 2020, 2, 5, 1839–1847
N Zivic, N Sadaba, N Almandoz, F Ruipérez, D Mecerreyes, H Sardon
Thioxanthone-Based Photobase Generators for the Synthesis of Polyurethanes via the Photopolymerization of Polyols and Polyisocyanates
Macromolecules 2020, 53, 6, 2069–2076
C Jehanno, J Demarteau, D Mantione, M C Arno, F Ruipérez, J L Hedrick, A P Dove, H Sardon
Synthesis of Functionalized Cyclic Carbonates through Commodity Polymer Upcycling
ACS Macro Lett. 2020, 9, 4, 443–447
E Gabirondo, A Sangroniz, A Etxeberria, Se Torres-Giner, H Sardon
Poly (hydroxy acids) derived from the self-condensation of hydroxy acids: from polymerization to end-of-life options
Polym. Chem., 2020, 11, 4861-4874
I Arandia, LMeabe, N Aranburu, H Sardon, D Mecerreyes, A J Müller
Influence of Chemical Structures on Isodimorphic Behavior of Three Different Copolycarbonate Random Copolymer
Series Macromolecules 2020, 53, 2, 669–681
I Flores, A Martínez de Ilarduya, H Sardon, A J Müller, S Muñoz-Guerra*
ROP and crystallization behaviour of partially renewable triblock aromatic-aliphatic copolymers derived from L-lactide
Eur. Polym. J. 2020, 122, 109321
2019
C Jehanno, L Mezzasalma, H Sardon, F Ruipérez, O Coulembier and D Taton
Benzoic Acid as an Efficient Organocatalyst for the Statistical Ring-Opening Copolymerization of ε-Caprolactone and L-Lactide: A Computational Investigation
Macromolecules 2019, 52, 23, 9238–9247
https://doi.org/10.1021/acs.macromol.9b01853
J P K. Tan, J Tan, N Park, K Xu, E D Chan, C Yang, V A Piunova, Z Ji, A Lim, J Shao, A Bai, X Bai, D Mantione, H Sardon, Y Y Yang, J L Hedrick
Upcycling Poly(ethylene terephthalate) Refuse to Advanced Therapeutics for the Treatment of Nosocomial and Mycobacterial Infections
Macromolecules 2019, 52, 20, 7878-7885
https://doi.org/10.1021/acs.macromol.9b01333
A Basterretxea, C Jehanno, D Mecerreyes, Haritz Sardon
Dual Organocatalysts Based on Ionic Mixtures of Acids and Bases: A Step Toward High temperature Polymerizations
ACS Macro Lett. 2019 8, 1055-1062
https://doi.org/10.1021/acsmacrolett.9b00481
I Flores, A Basterrexea, A Etxeberria, C Ocando, J F Vega, J M Salazar, H Sardon, A J Muller
Organocatalyzed Polymerization of PET-mb-poly(oxyhexane) Copolymers and Their Self-Assembly into Double Crystalline
Macromolecules 2019, 52, 18, 6834–6848
https://doi.org/10.1021/acs.macromol.9b01110
A Sangroniz, J-B Zhu, X Tang, A Etxeberria, E Y.-X. Chen, H Sardon
Packaging materials with desired mechanical and barrier properties and full chemical recyclability
Nat. Comm 10, 3559 (2019)
https://doi.org/10.1038/s41467-019-11525-x
J Wong, A T Gong, P A Defnet, L Meabe, B Beauchamp, R M Sweet, H Sardon, C L Cobb, A Nelson
3D Printing Ionogel Auxetic Frameworks for Stretchable Sensors Advanced
Materials Technologies 2019, 4, 9, 1900452
https://doi.org/10.1002/admt.201900452
N Fanjul-Mosteirín, C Jehanno, F Ruipérez, H Sardon, A P Dove
Rational Study of DBU Salts for the CO2 Insertion into Epoxides for the Synthesis of Cyclic Carbonates
ACS Sustainable Chem. Eng. 2019, 7, 12 10633-10640
https://doi.org/10.1021/acssuschemeng.9b01300
A Basterretxea, E Gabirondo, I Flores, A Etxeberria, A Gonzalez, A J Müller, D Mecerreyes, O Coulembier and H Sardon
Isomorphic Polyoxyalkylene Copolyethers Obtained by Copolymerization of Aliphatic Diols
Macromolecules 2019, 52, 9, 3506–3515
https://doi.org/10.1021/acs.macromol.9b00469
C Jehanno and H Sardon
Dynamic polymer network points the way to truly recyclable plastics
Nature 568, 467-468 (2019)
https://doi.org/10.1038/d41586-019-01209-3
I Flores, A Etxeberria , L Irusta, I Calafel, J. F Vega, J Martínez-Salazar, H Sardon and A J Müller
PET-ran-PLA Partially Degradable Random Copolymers Prepared by Organocatalysis: Effect of Poly(l-lactic acid) Incorporation on Crystallization and Morphology ACS Sustainable
Chem. Eng. 2019, 7, 9, 8647-8659
https://doi.org/10.1021/acssuschemeng.9b00443
A Bossion, I Olazabal, R H Aguirresarobe, S Marina, J Martín, L Irusta, D Taton and H Sardon
Synthesis of self-healable waterborne isocyanate-free poly(hydroxyurethane)-based supramolecular networks by ionic interactions
Polym. Chem., 2019,10, 2723-2733
https://doi.org/10.1039/C9PY00439D
F Tabatabaee, M Khorasani, M Ebrahimi, A González, L Irusta and H Sardon
Synthesis and comprehensive study on industrially relevant flame retardant waterborne polyurethanes based on phosphorus chemistry
Prog. Org. Coat. 2019, 131, 397-406
https://doi.org/10.1016/j.porgcoat.2019.02.042
I Flores, A Martínez de Ilarduya, H Sardon , A J Müller and S Muñoz-Guerra
Synthesis of Aromatic–Aliphatic Polyesters by Enzymatic Ring Opening Polymerization of Cyclic Oligoesters and their Cyclodepolymerization for a Circular Economy ACS
ACS Appl. Polym. Mater. 2019, 1, 3, 321–325
https://doi.org/10.1021/acsapm.8b00265
A Basterretxea, E Gabirondo, C Jehanno, H Zhu, I Flores, A J Müller, A Etxeberria, D Mecerreyes, O Coulembier and H Sardon
Polyether Synthesis by Bulk Self-Condensation of Diols Catalyzed by Non-Eutectic Acid−Base Organocatalysts
ACS Sust. Chem. Eng., 2019, 7, 4, 4103–4111
https://doi.org/10.1021/acssuschemeng.8b05609
N Zivic, P K Kuroishi, F Dumur, D Gigmes, A P Dove, H Sardon
Recent Advances and Challenges in the Design of Organic Photoacid and Photobase Generators for Polymerizations
Angew. Chem., 2019, 58, 31, 10410-10422
https://doi.org/10.1002/anie.201810118
A Bossion, K V Heifferon, L Meabe, N Zivic, D Taton, J L Hedrick, T E Long, H Sardon*
Opportunities for organocatalysis in polymer synthesis via step-growth methods
Prog Polym Sci 2019, 90, 164-210
https://doi.org/10.1016/j.progpolymsci.2018.11.003
C Jehanno, M M Pérez-Madrigal, J Demarteau, H Sardon and A P. Dove
Organocatalysis for depolymerisation
Polym. Chem., 2019,10, 172-186
2018
E Verde-Sesto, N Goujon, H Sardon, P Ruiz, T Vu Huynh, F Elizalde, D Mecerreyes, M Forsyth, L A O´Dell
DNP NMR Studies of Crystalline Polymer Domains by Copolymerization with Nitroxide Radical Monomers
Macromolecules, 2018, 51 (20), 8046-8053
https://doi.org/10.1021/acs.macromol.8b01665
H Sardon and A P Dove
Plastic recycling with a difference
Science 2018, Vol. 360, Issue 6387, 380-381
https://doi.org.10.1126/science.aat4997
A Bossion, R H Aguirresarobe, L Irusta, D Taton, H Cramail, E Grau, D Mecerreyes, C Su, G Liu, A J Müller, H Sardon
Unexpected Synthesis of Segmented Poly(hydroxyurea-urethane)s from Dicyclic Carbonates and Diamines by Organocatalysis
Macromolecules, 2018, 51 (15), 5556-5566
https://doi.org/10.1021/acs.macromol.8b00731
A Y Yuen, A Bossion, A Veloso, D Mecerreyes, J L Hedrick, A P Dove and H Sardon
Efficient polymerization and post-modification of N-substituted eight-membered cyclic carbonates containing allyl groups
Polym. Chem., 2018,9, 2458-2467
https://doi.org/10.1039/C8PY00231B
I Flores, J Demarteau, A J Muller, A Etxeberria, L Irusta, F Bergman, C Koning, H Sardon
Screening of Different Organocatalysts for the Sustainable Synthesis of PET
Eur Polym J. 2018,104, 170-176
https://doi.org/10.1016/j.eurpolymj.2018.04.040
N Sadaba, M Salsamendi, N Casado, E Zuza, J Muñoz, J-R Sarasua, D Mecerreyes, D Mantione, C Detrembleur, H Sardon
Catechol End-Functionalized Polylactide by Organocatalyzed Ring-Opening Polymerization
Polymers 2018, 10(2), 155
https://doi.org/10.3390/polym10020155
L Meabe, T Vu Huynh, N Lago, H Sardon, C M Li, L A O’Dell, M Armand, M Forsyth, D Mecerreyes
Poly(ethylene oxide carbonates) solid polymer electrolytes for lithium batteries
Electrochimica Acta 2018, 367-375
https://doi.org/10.1016/j.electacta.2018.01.101
A Y Yuen, L Porcarelli, R H Aguirresarobe, A Sanchez-Sanche, I del Agua, U Ismailov, G G Malliaras, D Mecerreyes, E Ismailova, H Sardon
Biodegradable Polycarbonate Iongels for Electrophysiology Measurements
Polymers 2018, 10(9), 989
https://doi.org/10.3390/polym10090989
C Jehanno, I Flores, A P Dove, A J Müller, F Ruipérez, H Sardon
Organocatalaysed depolymerisation of PET in a fully sustainable cycle using thermally stable protic ionic salt
Green Chem. 2018, 20, 1205-1212
2017
Preparation of Biodegradable Cationic Polycarbonates and Hydrogels through the Direct Polymerization of Quaternized Cyclic Carbonates
ACS Biomater. Sci. Eng 2017, 3, 8, 1567–1575
https://doi.org/10.1021/acsbiomaterials.7b00335
L Meabe, H Sardon, D Mecerreyes
Hydrolytically degradable poly(ethylene glycol) based polycarbonates by organocatalyzed condensation
Eur. Polym. J. 2017, 95, 737-745
https://doi.org/10.1016/j.eurpolymj.2017.06.046
E Udabe, M Isik, H Sardon, L Irusta, M Salsamendi, Z Sun, Z Zheng, F Yan, D Mecerreyes
Antimicrobial polyurethane foams having cationic ammonium groups
J. Appl. polym Sci. 2017, 134, 45, 45473
https://doi.org/10.1002/app.45473
D Mantione, N Casado, A Sanchez-sanchez, H Sardon, D Mecerreyes
Easy-to-make carboxylic acid dioxythiophene monomer (ProDOT-COOH) and functional conductive polymers
Polym. Chem. 2017, 55, 17, 2721-2724
https://doi.org/10.1002/pola.28690
L I Roncoa, A Basterretxea, D Mantione, R H Aguirresarobe, R J Minari, L M Gugliotta, D Mecerreyes, H Sardon
Temperature responsive PEG-based polyurethanes “à la carte”
Polymer 2017, 122, 117-124
https://doi.org/10.1016/j.polymer.2017.06.043
X An, R H Aguirresarobe, L Irusta, F Ruipérez, J M Matxain, X Pan, N Aramburu, D Mecerreyes, H Sardon, Jian Zhu
Aromatic diselenide crosslinkers to enhance the reprocessability and self-healing of polyurethane thermosets
Polym. Chem. 2017, 8, 3641-3646
https://doi.org/10.1039/C7PY00448F
A Basterretxea, E Gabirondo, A Sanchez-Sanchez, A Etxeberria, O Coulembier, D Mecerreyes, H Sardon
Synthesis and characterization of poly (e-caprolactam-co-lactide) polyesteramides using Brønsted acid or Brønsted base organocatalyst
Eur. Polym. J 2017, 95, 650-659
https://doi.org/10.1016/j.eurpolymj.2017.05.023
D Mantione, I del Agua, W Schaafsma, M ElMahmoudy, I Uguz, A Sanchez-Sanchez, H Sardón, B Castro, G G Malliaras, David Mecerreyes
Low temperature cross-linking of PEDOT:PSS films using divinylsulfone
ACS applied and interfaces 2017, 9, 21, 18254–18262
https://doi.org/10.1021/acsami.7b02296
J P K Tan, D J Coady, H Sardon, A Yuen, S Venkataraman, A C Engler, R Ono, Y Y Yang, J L Hedrick
Broad spectrum macromolecular antimicrobials with biofilm disruption capability and in vivo efficacy
Adv. Health. Mater. 2017, 6, 16, 1601420
https://doi.org/10.1002/adhm.201601420
L Porcarelli, K Manojkumar, H Sardon, O Llorente, A S Shaplove, K Vijayakrishna, C Gerbaldi, D Mecerreyes
Single Ion Conducting Polymer Electrolytes Based on Versatile Polyurethanes
Electrochimica Acta 241 (2017) 526-534
https://doi.org/10.1016/j.electacta.2017.04.132
S Garmendia, D Mantione, S Alonso-de Castro, C Jehanno, L Lezama, J L Hedrick, D Mecerreyes, L Salassa and Ha Sardon
Polyurethane based organic macromolecular contrast agents (PU-ORCAs) for magnetic resonance imaging
Polym. Chem. 2017, 8, 2693-2701
https://doi.org/10.1039/C7PY00166E
Le eabe, N Lago, L Rubatat, C Li, A J Müller, H Sardon, M Armand, D Mecerreyes
Polycondensation as a Versatile Synthetic Route to Aliphatic Polycarbonates for Solid Polymer Electrolytes
Electrochimica Acta 237 (2017) 259–266
https://doi.org/10.1016/j.electacta.2017.03.217
Sofia M. Morozova, Alexander S. Shaplov, Elena I. Lozinskaya, Petr S. Vlasov, Haritz Sardon, David Mecerreyes and Yakov S. Vygodskii
Poly(ionic liquid)-based polyurethanes having imidazolium, ammonium, morpholinium, or pyrrolidonium cations
High Performance Polymers
https://doi.org/10.1177/0954008317701551
A Sanchez-Sanchez, I Rivilla, M Agirre, A Basterretxea, A Etxeberria, A Veloso, H Sardon, D Mecerreyes, Fernando P. Cossio
Enantioselective Ring-Opening Polymerization of rac-Lactide Dictated by Densely Substituted Aminoacids
J. Am. Chem. Soc., 2017, 139 (13), pp 4805–4814.
https://doi.org/10.1021/jacs.6b13080
S Morozova, A Shaplov, E Lozinskaya, D Mecerreyes, H Sardon, S Zulfiqar, F Suárez-García, Y Vygodskii
Ionic polyurethanes as new family of poly(ionic liquid)s for efficient CO2 capture
Macromolecules, 2017, 50 (7), pp 2814–2824
https://doi.org/10.1021/acs.macromol.6b02812
J M W Chan, R J Wojtecki, H Sardon, A L Z Lee, C E Smith, A Shkumatov, S Gao, H Kong, Y Y Yang, J L Hedrick
Self-Assembled, Biodegradable Magnetic Resonance Imaging Agents: Organic Radical-Functionalized Diblock Copolymers
ACS Macro Lett., 2017, 6, pp 176–180
https://doi.org/10.1021/acsmacrolett.6b00924
A Bossion, G O Jones, D Taton, D Mecerreyes, J L Hedrick, Z Y Ong, Y Y Yang, H Sardon
Non-Isocyanate Polyurethane Soft Nanoparticles Obtained by Surfactant-Assisted Interfacial Polymerization
Langmuir, 2017, 33 (8), pp 1959–1968
https://doi.org/10.1021/acs.langmuir.6b04242
H Daemi, M Barikani, H Sardon
Transition-metal-free synthesis of supramolecular ionic alginate-based polyurethanes
Carbohydr. Polym. 2017, 157, 1949-1954
https://doi.org/10.1016/j.carbpol.2016.11.086
M Isik, M Agirre, J Zarate, G Puras, D Mecerreyes, H Sardon, J L Pedraz
Amine Containing Cationic Methacrylate Copolymers as Efficient Gene Delivery Vehicles to Retinal Epithelial Cells
Polym. Sci., Part A 2017, 2, 280-287
https://doi.org/10.1002/pola.28376
M Ribeiro, M P Ferraz, F J Monteiro, M H Fernandes, M M Beppu, D Mantione, Haritz Sardon
Antibacterial silk fibroin/nanohydroxyapatite hydrogels with silver and gold nanoparticles for bone regeneration Nanomedicine
Nanomedicine 2017, 13(1,) 231-239
2016
A Basterretxea, Y Haga, A Sanchez-Sanchez, M Isik, L Irusta, M Tanaka, K Fukushima, Haritz Sardon
Biocompatibility and hemocompatibility evaluation of polyether urethanes synthesized using DBU organocatalyst
Eur. Polym. J. 2016, 84, 750-758
https://doi.org/10.1016/j.eurpolymj.2016.08.008
M Isik, J P K Tan, R J Ono, A Sanchez-Sanchez, D Mecerreyes, Y Y Yang, J L Hedrick, H Sardon
Tuning the antimicrobial properties of biodegradable polycarbonates by simple anion-exchange reactions
Macro. Biosci. 2016, 16, 1360-1367
https://doi.org/10.1002/mabi.201600090
J Fernández, H Amestoy, H Sardon, M Aguirre, A Larrañaga Varga, Jose-Ramon Sarasua
Effect of the molecular weight on the mechanical properties an crystallization of poly(ethylene brassylate) homopolymers
J Mech. Behav. Biomed. Mater. 2016, 64, 209-219
https://doi.org/10.1016/j.jmbbm.2016.07.031
J S Desport, D Mantione, M Moreno, H Sardón, M J Barandiaran, D Mecerreyes
Synthesis of three different galactose-based methacrylate monomers for the production of sugar-based polymers
Carbohydrate research 2016, 232, 50-54
https://doi.org/10.1016/j.carres.2016.06.008
D Mantione, I del Agua, W Schaafsma, J Diez-Garcia, B Castro, H Sardon, D Mecerreyes
Poly(3,4-ethylenedioxythiophene):GlycosAminGlycan (PEDOT:GAG) aqueous Dispersions: Towards Electrically Conductive Bioactive Materials for Neural Interfaces
Macro. Biosci 2016, 16, 1227-1238
https://doi.org/10.1002/mabi.201600059
A Sanchez-Sanchez, A Basterretxea, D Mantione, A Etxeberria, C Elizetxea, A de la Calle, S García-Arrieta, H Sardon, D Mecerreyes
Organo-mediated bulk polymerization of ε-Caprolactam and its Copolymerization with ε-Caprolactone using sulfonic acids
J. Polym. Sci., Part A 2016, 54, 2394-2402
https://doi.org/10.1002/pola.28114
J M W Chan, J P K Tan, A C Engler, X Ke, S Gao, C Yang, H Sardon, Y Y Yang, J L Hedrick
Anticancer Drug Loading of Degradable Polymeric Mixed Micelles via a Biomimetic Mechanism
Macromolecules, 2016, 49 (6), 2013–2021
https://doi.org/10.1021/acs.macromol.5b02784
M Isik, F Ruiperez, H Sardon, A Gonzalez, S Zulfiqar, D Mecerreyes
Innovative Poly(ionic liquid)s by the Polymerization of Deep Eutectic Monomers
Macro. Rapid Comm., 2016, 37, 1135–1142
https://doi.org/10.1002/marc.201600026
A Yuen, A Bossion, E Gómez-Bengoa, F Ruipérez, M Isik, J L Hedrick, D Mecerreyes, Y Y Yang, H Sardon
Room temperature synthesis of isocyanate free poly(hydroxyurethanes) using highly reactive N-substituted 8-membered cyclic carbonates.
Polym. Chem. 2016, 7, 2105-2111
https://doi.org/10.1039/C6PY00264A
H Daemi, S Rajabi-Zeleti, H Sardon, M Barikani, A Khademhosseini, H Baharvand
A Robust Super-Tough Biodegradable Elastomer Engineered by Supramolecular Ionic Interactions.
Biomaterials 2016, 84, 54-63
https://doi.org/10.1016/j.biomaterials.2016.01.025
W N Ottou, H Sardon, D Mecerreyes, J Vignolle, D Taton
Update and challenges in organo-mediated polymerization reactions
Prog. Polym. Sci. 2016, 56, 64–115
https://doi.org/10.1016/j.progpolymsci.2015.12.001
N Casado, G Hernández, H Sardon, D Mecerreyes
Current Trends in Redox Polymers for Energy and Nanomedicine
Prog. Polym. Sci. 2016, 52, 107-135
https://doi.org/10.1016/j.progpolymsci.2015.08.003
2015
S Venkataraman, V W L Ng, D J Coady, H W Horn, G O Jones, T S Fung, H Sardon, R M Waymouth, J L Hedrick, Y Y Yang
A Simple and Facile Approach to Functional Eight-Membered Aliphatic Cyclic Carbonates and Their Organo-catalytic Polymerization.
J. Am. Chem. Soc.2015, 137, 13851-13860
https://doi.org/10.1021/jacs.5b06355
M Isik, T Lonjaret, H Sardon, R Marcilla, T Herve, G G Malliaras, E Ismailova, D Mecerreyes
Cholinium Based Ion Gels as Electrolytes for Long-Term Cutaneous Recordings.
Mater. Chem. C, 2015, 3, 8942-8948
https://doi.org/10.1039/C5TC01888A
H Sardon, J P K Tan, J M W Chan, D Mantione, D Mecerreyes, J L Hedrick, Y Y Yang
Thermoresponsive Random Poly(ether urethane) based Nanoparticles with Tailorable LCSTs for Anticancer Drug Delivery.
Macromol. Rapid Comm. 2015, 36 (19), 1761-1767
https://doi.org/10.1002/marc.201500247
H Sardon, A Pascual, D Mecerreyes, D Taton, H Cramail, J L Hedrick
Synthesis of Polyurethanes using Organocatalysis: A Perspective
Macromolecules 2015, 48, 3153−3165
https://doi.org/10.1021/acs.macromol.5b00384
A Pascual, J P K Tan, A Yuen, J M W Chan, D J Coady, D Mecerreyes, J L Hedrick, Y Y Yang, H Sardon
Broad-Spectrum Antimicrobial Polycarbonate Hydrogels with Fast Degradability
Biomacromolecules 2015, 16 (4), 1169–1178
https://doi.org/10.1021/bm501836z
Q Xu, H Sardon, J M W Chan, J L Hedrick, Y Y Yang
Polyurethane-coated silica particles with broad-spectrum antibacterial properties
Polym. Chem. 2015,6, 2011–2022
https://doi.org/10.1039/C4PY01455C
H Sardon, A González, M J Fernández-Berridi, L. Irusta
Oxygen Barrier Properties of Waterborne Polyurethane/Silica Hybrids
J. Macromol. Sci. B. 2015, 54, 711-721
https://doi.org/10.1080/00222348.2015.1035613
J M W Chan, X Zhang, M K Brennan, H Sardon, A C Engler, C H Fox, C W Frank, R M Waymouth, J L Hedrick
Organocatalytic Ring-Opening Polymerization of Trimethylene Carbonate to Yield a Biodegradable Polycarbonate
J. Chem. Educ., 2015, 92 (4), 708–713
https://doi.org/10.1021/ed500595k
A Pascual, H Sardón, F Ruipérez, R Gracia, P Sudam, A Veloso, D Mecerreyes
Experimental and Computational Studies of Ring Opening Polymerization of Ethylene Brassylate Macrolactone and Copolymerization with ε-caprolactone and TBD-guanidine Organic Catalyst
J. Polym. Sci., Part A: Polym. Chem. 2015, 53 (4), 552-561
https://doi.org/10.1002/pola.27473
2014
V W L Ng, et al.
Antimicrobial hydrogels: a new weapon in the arsenal against multidrug-resistant infections
Adv. Drug Delivery Rev. 2014, 78, 46-62
https://doi.org/10.1016/j.addr.2014.10.028
M Isik, et al.
New amphiphilic block copolymers from lactic acid and cholinium building units
RSC Adv. 2014, 4, 53407-53410
https://doi.org/10.1039/C4RA10063H
A Pascual, et al.
Organocatalyzed Synthesis of Aliphatic Polyesters from Ethylene Brassylate: a Cheap and Renewable Macrolactone
ACS Macro Lett. 2014, 3 (9), 849-853
https://doi.org/10.1021/mz500401u
M Isik, et al.
Ionic Liquids and Cellulose: Dissolution, Chemical Modification and Preparation of New Celullosic Materials
Int. J. Mol. Sci. 2014, 15, 11922-11940
https://doi.org/10.3390/ijms150711922
J M W Chan, et al.
Chemically Modifiable N-Heterocycle-functionalized Polycarbonates as a Platform for Diverse Smart Biomimetic Nanomaterials
Chem. Sci. 2014, 5, 3294-3300
https://doi.org/10.1039/C4SC00789A
H Sardon, et al.
Polymer/silica nanohybrids by means of tetraethoxysilane sol–gel condensation onto waterborne polyurethane particles.
Prog. Org. Coat. 2014, 77, 1436–1442
http://dx.doi.org/10.1016/j.porgcoat.2014.04.032
H Sardon, et al.
Highly Tunable Polyurethanes: Organocatalyzed Polyaddition and Subsequent Post-polymerization Modification of Pentafluorophenyl Ester Sidechains.
Polym. Chem. 2014, 5, 3547-3550
https://doi.org/10.1039/C4PY00262H
D P Sanders, et al.
Synthesis of functionalized cyclic carbonate monomers using a versatile pentafluorophenyl carbonate intermediate.
Polym. Chem. 2014, 5(2), 327-329
https://doi.org/10.1039/C3PY01128C
2013
H Sardon, et al.
Organic Acid-Catalyzed Polyurethane Formation via a Dual-Activated Mechanism: Unexpected Preference of N‐Activation overO‐Activation of Isocyanates.
J. Am. Chem. Soc. 2013, 135, 16235−16241
https://dx.doi.org/10.1021/ja408641g
J M W Chan, et al.
Tetra-n-butylammonium Fluoride as an Efficient Transesterification Catalyst for the Functionalization of Cyclic Carbonates and Aliphatic Polycarbonates.
ACS Macro Lett., 2013, 2(10) 860–864
https://doi.org/10.1021/mz400334j
A Pascual, et al.
Organocatálisis: hacia una nueva generación de catalizadores para la síntesis de polímeros
Anales de Química 2013, 109(3), 173–181
H Sardon, et al.
Waterborne hybrid polyurethane coatings functionalized with (3-aminopropyl)triethoxysilane: Adhesion properties.
Prog. Org. Coat. 2013, 76, 1230–1235
https://doi.org/10.1016/j.porgcoat.2013.03.025
H Sardon, et al.
Homogeneous isocyanate-and catalyst-free synthesis of polyurethanes in aqueous media.
Green Chem., 2013, 15, (5), 1121-1126
https://doi.org/10.1039/C3GC40319J
D J Coady, et al.
Polymerizing Base Sensitive Cyclic Carbonates Using Acid Catalysis
ACS Macro Lett.2013,2(4),306-312
https://doi.org/10.1021/mz3006523
A C Engler, et al.
Accessing New Materials through Polymerization and Modification of a Polycarbonate with a Pendant Activated Ester.
Macromolecules 2013, 46 (4),1283-1290