2022
Most recent scientific publications
H Sardon, T Long, H Le Ferrand
Sustainable Additive Manufacturing of Plastics
ACS Sustainable Chemistry & Engineering 2022, 10 (6), 1983-1985


A Sangroniz, JB Zhu, A Etxeberria, EYX Chen, H Sardon
Modulating the crystallinity of a circular plastic towards packaging material with outstanding barrier properties
Macromolecular Rapid Communications 2022, 2200008

C Jehanno, JW Alty, M Roosen, S De Meester, AP Dove, E Chen, FA Leibfarth, H Sardon
Critical advances and future opportunities in upcycling commodity polymers.
Nature. 2022, 603, p. 803-814.

MR Caputo, X Tang, AH Westlie, H Sardon, EY-X Chen, AJ Müller.
Effect of Chain Stereoconfiguration on Poly(3-hydroxybutyrate) Crystallization Kinetics.
Biomacromolecules. 2022, 23 (9), p. 3847-3859.

A Dominguez, M Criado, E Gabirondo, H Lasa, JL Olmedo, N Casado, N Alegret, AJ Müller, H Sardon, A Vallejo, D Mecerreyes.
Electroactive 3D printable poly(3,4-ethylenedioxythiophene)-graft-poly(epsilon-caprolactone) copolymers as scaffolds for muscle cell alignment.
Polym. Chem. 2022, 13 (1), p. 109-120.


A Gomez, N Ayensa, B Grignard, L Irusta, I Calvo, AJ Müller, C Detrembleur, H Sardon.
Enhanced and Reusable Poly(hydroxy urethane)-Based Low Temperature Hot-Melt Adhesives.
Acs Polymers Au. 2022, 2 (3), p. 194-207

S Atia, K Zeggagh, S Hadjout, A Etxeberria, Z Benabdelghani.
Enhancement of semiconducting and thermomechanical properties of materials based on polyaniline and polyvinylpyrrolidone.
J. Polym. Res. 2022, 29 (4), 138.

I Olazabal, N Goujon, D Mantione, M Alvarez, C Jehanno, D Mecerreyes, H Sardon.
From plastic waste to new materials for energy storage.
Polym. Chem. 2022, 13(29), p. 4222-4229.

A Hernández, HA Houck, F Elizalde, M Guerre, H Sardon, FE Du.
Internal catalysis on the opposite side of the fence in non-isocyanate polyurethane covalent adaptable networks.
Eur Polym J. 2022, 168, 111100.


A Sangroniz, L Sangroniz, S Hamzehlou, N Aranburu, H Sardon, JR Sarasua, M Iriarte, JR Leiza, A Etxeberria.
Lactide-valerolactone copolymers for packaging applications.
Polym. 2022, 14 (1), p. 52.

G Damonte, L Maddalena, A Fina, D Cavallo, AJ Müller, MR Caputo, A Mariani, O Monticelli.
On novel hydrogels based on poly(2-hydroxyethyl acrylate) and polycaprolactone with improved mechanical properties prepared by frontal polymerization.
Eur Polym J. 2022, 171, 111226.

F Elizalde, J Amici, S Trano, G Vozzolo, R Aguirresarobe, D Versaci, S Bodoardo, D Mecerreyes, H Sardon, F Bella.
Self-healable dynamic poly(urea-urethane) gel electrolyte for lithium batteries.
J. Mater. Chem. A. 2022, 10 (23), p. 12588-12596.

M Valle, M Ximenis, X Lopez de Pariza, JMW Chan, H Sardon.
Spotting Trends in Organocatalyzed and Other Organomediated (De)polymerizations and Polymer Functionalizations.
Angew. Chem. Int. Ed. 2022, 61 (36), e202203043.


SE Fenni, MR Caputo, AJ Müller, D Cavallo.
Surface Roughness Enhances Self-Nucleation of High-Density Polyethylene Droplets Dispersed within Immiscible Blends.
Macromolecules. 2022, 55 (4), p. 1412-1423.

DE Fagnani, C Jehanno, H Sardon, AJ McNeil.
Sustainable Green Polymerizations and End-of-Life Treatment of Polymers.
Macromol. Rapid Commun. 2022, 43(13), 2200446.

XL de Pariza, T Erdmann, PL Arrechea, L Perez, C Dausse, NH Park, JL Hedrick, H Sardon.
Synthesis of Tailored Segmented Polyurethanes Utilizing Continuous-Flow Reactors and Real-Time Process Monitoring.
Chem. Mater. 2021, 33 (20), p. 7986-7993.


I Flores, RA Perez, E Gabirondo, MR Caputo, GM Liu, DJ Wang, H Sardon, AJ Müller.
Unexpected Structural Properties in the Saturation Region of the Odd-Even Effects in Aliphatic Polyethers: Influence of Crystallization Conditions.
Macromolecules. 2022, 55. (2), p. 584-594.

F Siragusa, J Demarteau, T Habets, I Olazabal, K Robeyns, G Evano, R Mereau, T Tassaing, B Grignard, H Sardon, C Detrembleur.
Unifying Step-Growth Polymerization and On-Demand Cascade Ring-Closure Depolymerization via Polymer Skeletal Editing.
Macromolecules. 2022, 55. (11), p. 4637-4646.

2021
A Dominguez, E Gabirondo, N Alegret, CM De León, R Hernandez, A Vallejo, M Prato, D Mecerreyes.
3D Printable Conducting and Biocompatible PEDOT-graft-PLA Copolymers by Direct Ink Writing.
Macromol. Rapid Commun. 2021, 42 (12), 2100100.

A Gallastegui, E Gabirondo, F Elizalde, N Aranburu, D Mecerreyes, H Sardon.
Chemically recyclable glycerol-biobased polyether thermosets.
Eur Polym J. 2021, 143, 110174.

RA Perez, L Meabe, G Liu, H Sardon, Y Zhao, D Wang, AJ Müller.
Even-Odd Effect in Aliphatic Polycarbonates with Different Chain Lengths: from Poly (Hexamethylene Carbonate) to Poly (Dodecamethylene Carbonate).
Macromolecules. 2021, 54 (1), p. 259-271.

EM Niemczyk, A Gomez, JRN Haler, G Frache, H Sardon, R Quintana.
Insights on the atmospheric-pressure plasma-induced free-radical polymerization of allyl ether cyclic carbonate liquid layers.
Polym. 2021, 13 (17), 2856.

E Carmeli, SE Fenni, MR Caputo, AJ Müller, D Tranchida, D Cavallo.
Surface Nucleation of Dispersed Polyethylene Droplets in Immiscible Blends Revealed by Polypropylene Matrix Self-Nucleation.
Macromolecules. 2021, 54 (19), p. 9100-9112.

A Gomez, F Elizalde, I Calvo, H Sardon.
Trends in non-isocyanate polyurethane (NIPU) development.
Chem. Commun. 2021, 57 (92), p. 12254-12265.

M Safari, I Otaegi, N Aramburu, G Guerrica, AM De Ilarduya, H Sardon, AJ Müller.
Synthesis, structure, crystallization and mechanical properties of isodimorphic PBS-ran-PCL copolyesters
Polym. 2021, 13 (14), 2263.

R A Pérez-Camargo, G Liu, L Meabe, Y Zhao, H Sardon, A J Müller, D Wang
Using Successive Self-Nucleation and Annealing to Detect the Solid–Solid Transitions in Poly (hexamethylene carbonate) and Poly (octamethylene carbonate)
Macromolecules 2021, 54 (20), p. 9670-9680.

N Fanjul-Mosteirín, R Aguirresarobe, N Sadaba, A Larrañaga, E Marin, J Martin, N Ramos-Gomez, M C Arno, H Sardon, A P Dove
Crystallization-Induced Gelling as a Method to 4D Print Low-Water-Content Non-isocyanate Polyurethane Hydrogels
Chemistry of materials 2021, 33 (18), 7194–7202

H Sardon, D Mecerreyes, A Basterretxea, L Avérous, C Jehanno
From Lab to Market: Current Strategies for the Production of Biobased Polyols
ACS Sustainable Chemistry & Engineering 2021, 9 (32), 10664-10677

R A Pérez-Camargo, G Liu, L Meabe, Y Zhao, H Sardon, D Wang, A J Müller
Solid–Solid Crystal Transitions (δ to α) in Poly(hexamethylene carbonate) and Poly(octamethylene carbonate)
Macromolecules 2021, 54 (15), 7258-7268.

A Gomez-Lopez, S Panchireddy, B Grignard, I Calvo, C Jerome, C Detrembleur, H Sardon
Poly (hydroxyurethane) Adhesives and Coatings: State-of-the-Art and Future Directions
ACS Sustainable Chem. Eng. 2021, 9(29), 9541–9562

M Safari, I Otaegi, N Aramburu, G Guerrica-Echevarria, A Martínez Martínez de Ilarduya, H Sardon, A J Müller
Synthesis, Structure, Crystallization and Mechanical Properties of Isodimorphic PBS-ran-PCL Copolyesters
Polymers 2021, 13(14), 2263

X Lopez de Pariza, E Cordero Jara, N Zivic, F Ruipérez, T E Long, H Sardon
Novel imino- and aryl-sulfonate based photoacid generators for the cationic ring-opening polymerization of ε-caprolactone
Polym. Chem., 2021, 12, 4035-4042

J L Olmedo-Martínez, M Pastorio, E Gabirondo, A Lorenzetti, H Sardon, D Mecerreyes, A J Müller
Polyether Single and Double Crystalline Blends and the Effect of Lithium Salt on Their Crystallinity and Ionic Conductivity
Polymers 2021, 13(13), 2097

O Llorente, A Agirre, I Calvo, M Olaso, R Tomovska, H Sardon
Exploring the advantages of oxygen-tolerant thiol-ene polymerization over conventional acrylate free radical photopolymerization processes for pressure-sensitive adhesives
Polym J 2021, 53, 1195–1204.


A Basterretxea, E Gabirondo, C Jehanno, H Zhu, O Coulembier, D Mecerreyes, H Sardon
Stereoretention in the Bulk ROP of l-Lactide Guided by a Thermally Stable Organocatalyst
Macromolecules 2021, 54, 13, 6214–6225

S Marina, A D Scaccabarozzi, E Gutierrez‐Fernandez, E Solano, A Khirbat, L Ciammaruchi, A Iturrospe, A Balzer, L Yu, E Gabirondo, X Monnier, H Sardon, T D Anthopoulos, M Caironi, M Campoy‐Quiles, C Müller, D Cangialosi, N Stingelin, Jaime Martin
Polymorphism in Non‐Fullerene Acceptors Based on Indacenodithienothiophene
Advanced Functional Materials 2021, 31, 29, 2103784

E Sanchez-Rexach, P T Smith, A Gomez-Lopez, M Fernandez, A L Cortajarena, H Sardon, A Nelson
3D-Printed Bioplastics with Shape-Memory Behavior Based on Native Bovine Serum Albumin
ACS Appl. Mater. Interfaces 2021, 13, 16, 19193–19199


C Jehanno, J Demarteau, D Mantione, M C Arno, F Ruiperez, J L Hendrick, A P Dove, H Sardon
Selective Chemical Upcycling of Mixed Plastics Guided by a Thermally Stable Organocatalyst
Angewandte Chemie International Edition 60 (12), 6710-6717

M Riechers, L Fanini, A Apicella, C B Galván, E Blondel, B Espiña, S Kefer, …
Plastics in our ocean as a transdisciplinary challenge
Marine Pollution Bulletin 164, 112051


A Gomez-Lopez, B Grignard, I Calvo, C Detrembleur, H Sardon
Synergetic Effect of Dopamine and Alkoxysilanes in Sustainable Non-Isocyanate Polyurethane Adhesives
Macromolecular Rapid Communications 42 (3), 2000538

R H Aguirresarobe, S Nevejans, B Reck, L Irusta, H Sardon, J M Asua, N Ballard
Healable and self-healing polyurethanes using dynamic chemistry
Progress in Polymer Science 114, 101362

A Gallastegui, E Gabirondo, F Elizalde, N Aranburu, D Mecerreyes, H Sardon
Chemically recyclable glycerol-biobased polyether thermosets
European Polymer Journal 143, 110174


V Montagna, J Takahashi, M Y Tsai, T Ota, N Zivic, S Kawaguchi, T Kato, M Tanaka, H Sardon, K Fukushima
Methoxy-Functionalized Glycerol-Based Aliphatic Polycarbonate: Organocatalytic Synthesis, Blood Compatibility, and Hydrolytic Property
ACS Biomaterials Science & Engineering 7 (2), 472-481


X Monnier, S Marina, X Lopez de Pariza, H Sardón, J Martin, D Cangialosi
Physical Aging Behavior of a Glassy Polyether
Polymers 13 (6), 954

E Gabirondo, B Melendez-Rodriguez, C Arnal, J M Lagaron, A Martínez de Ilarduya, H Sardon, S Torres-Giner
Organocatalyzed closed-loop chemical recycling of thermo-compressed films of poly (ethylene furanoate)
Polymer Chemistry 12 (10), 1571-1580


2020
K O’Harra, N Sadaba, M Irigoyen, F Ruipérez, R Aguirresarobe, H Sardon, J Bara
Nearly Perfect 3D Structures Obtained by Assembly of Printed Parts of Polyamide Ionene Self-Healing Elastomer
ACS Applied Polymer Materials 2020, 2, 11, 4352–4359
S M Morozova, E I Lozinskaya, H Sardon, F Suárez-García, P S.Vlasov, R Vaudemont, Y S Vygodskii, A S Shaplov
Ionic Polyureas—A Novel Subclass of Poly(Ionic Liquid)s for CO2 Capture
Membranes 2020, 10, 240
E Sanchez-Rexach, T G Johnston, C Jehanno, H Sardon, A Nelson
Sustainable Materials and Chemical Processes for Additive Manufacturing
Chem. Mater. 2020, 32, 17, 7105–7119
From plastic waste to polymer electrolytes for batteries through chemical upcycling of polycarbonate
J Mater Chem A 2020, 8, 13921-13926
J Demarteau, I Olazabal, C Jehanno, H Sardon
Aminolytic upcycling of poly(ethylene terephthalate) wastes using a thermally-stable organocatalyst
Polymer Chem 2020, 11, 4875-4882
L Sangroniz, A Sangroniz, L Meabe, A Basterretxea, H Sardon, D Cavallo, A J Müller
Chemical Structure Drives Memory Effects in the Crystallization of Homopolymers
Macromolecules 2020, 53, 12, 4874–4881
A Basterretxea, X Lopez de Pariza, E Gabirondo, S Marina, J Martin, A Etxeberria, D Mecerreyes, H Sardon
Synthesis and Characterization of Fully Biobased Copolyether Polyols
Ind. Eng. Chem. Res. 2020, 59, 23, 10746–10753
J Demarteau, K E O’Harra, J E Bara, H Sardon
Valorization of Plastic Wastes for the Synthesis of Imidazolium Based Self‐Supported Elastomeric Ionenes
ChemSusChem 2020, 13, 12, 3122-3126
J Huang, C Jehanno, J C Worch, F Ruipérez, H Sardon, A P Dove, O Coulembier
Selective Organocatalytic Preparation of Trimethylene Carbonate from Oxetane and Carbon Dioxide
ACS Catal. 2020, 10, 10, 5399–5404
A Gomez-Lopez, B Grignard, I Calvo, C Detrembleur, H Sardon
Monocomponent Non-isocyanate Polyurethane Adhesives Based on a Sol–Gel Process
ACS Appl. Polym. Mater. 2020, 2, 5, 1839–1847
N Zivic, N Sadaba, N Almandoz, F Ruipérez, D Mecerreyes, H Sardon
Thioxanthone-Based Photobase Generators for the Synthesis of Polyurethanes via the Photopolymerization of Polyols and Polyisocyanates
Macromolecules 2020, 53, 6, 2069–2076
C Jehanno, J Demarteau, D Mantione, M C Arno, F Ruipérez, J L Hedrick, A P Dove, H Sardon
Synthesis of Functionalized Cyclic Carbonates through Commodity Polymer Upcycling
ACS Macro Lett. 2020, 9, 4, 443–447
E Gabirondo, A Sangroniz, A Etxeberria, Se Torres-Giner, H Sardon
Poly (hydroxy acids) derived from the self-condensation of hydroxy acids: from polymerization to end-of-life options
Polym. Chem., 2020, 11, 4861-4874
I Arandia, LMeabe, N Aranburu, H Sardon, D Mecerreyes, A J Müller
Influence of Chemical Structures on Isodimorphic Behavior of Three Different Copolycarbonate Random Copolymer
Series Macromolecules 2020, 53, 2, 669–681
I Flores, A Martínez de Ilarduya, H Sardon, A J Müller, S Muñoz-Guerra*
ROP and crystallization behaviour of partially renewable triblock aromatic-aliphatic copolymers derived from L-lactide
Eur. Polym. J. 2020, 122, 109321
2019
C Jehanno, L Mezzasalma, H Sardon, F Ruipérez, O Coulembier and D Taton
Benzoic Acid as an Efficient Organocatalyst for the Statistical Ring-Opening Copolymerization of ε-Caprolactone and L-Lactide: A Computational Investigation
Macromolecules 2019, 52, 23, 9238–9247
https://doi.org/10.1021/acs.macromol.9b01853
J P K. Tan, J Tan, N Park, K Xu, E D Chan, C Yang, V A Piunova, Z Ji, A Lim, J Shao, A Bai, X Bai, D Mantione, H Sardon, Y Y Yang, J L Hedrick
Upcycling Poly(ethylene terephthalate) Refuse to Advanced Therapeutics for the Treatment of Nosocomial and Mycobacterial Infections
Macromolecules 2019, 52, 20, 7878-7885
https://doi.org/10.1021/acs.macromol.9b01333
A Basterretxea, C Jehanno, D Mecerreyes, Haritz Sardon
Dual Organocatalysts Based on Ionic Mixtures of Acids and Bases: A Step Toward High temperature Polymerizations
ACS Macro Lett. 2019 8, 1055-1062
https://doi.org/10.1021/acsmacrolett.9b00481
I Flores, A Basterrexea, A Etxeberria, C Ocando, J F Vega, J M Salazar, H Sardon, A J Muller
Organocatalyzed Polymerization of PET-mb-poly(oxyhexane) Copolymers and Their Self-Assembly into Double Crystalline
Macromolecules 2019, 52, 18, 6834–6848
https://doi.org/10.1021/acs.macromol.9b01110
A Sangroniz, J-B Zhu, X Tang, A Etxeberria, E Y.-X. Chen, H Sardon
Packaging materials with desired mechanical and barrier properties and full chemical recyclability
Nat. Comm 10, 3559 (2019)
https://doi.org/10.1038/s41467-019-11525-x
J Wong, A T Gong, P A Defnet, L Meabe, B Beauchamp, R M Sweet, H Sardon, C L Cobb, A Nelson
3D Printing Ionogel Auxetic Frameworks for Stretchable Sensors Advanced
Materials Technologies 2019, 4, 9, 1900452
https://doi.org/10.1002/admt.201900452
N Fanjul-Mosteirín, C Jehanno, F Ruipérez, H Sardon, A P Dove
Rational Study of DBU Salts for the CO2 Insertion into Epoxides for the Synthesis of Cyclic Carbonates
ACS Sustainable Chem. Eng. 2019, 7, 12 10633-10640
https://doi.org/10.1021/acssuschemeng.9b01300
A Basterretxea, E Gabirondo, I Flores, A Etxeberria, A Gonzalez, A J Müller, D Mecerreyes, O Coulembier and H Sardon
Isomorphic Polyoxyalkylene Copolyethers Obtained by Copolymerization of Aliphatic Diols
Macromolecules 2019, 52, 9, 3506–3515
https://doi.org/10.1021/acs.macromol.9b00469
C Jehanno and H Sardon
Dynamic polymer network points the way to truly recyclable plastics
Nature 568, 467-468 (2019)
https://doi.org/10.1038/d41586-019-01209-3
I Flores, A Etxeberria , L Irusta, I Calafel, J. F Vega, J Martínez-Salazar, H Sardon and A J Müller
PET-ran-PLA Partially Degradable Random Copolymers Prepared by Organocatalysis: Effect of Poly(l-lactic acid) Incorporation on Crystallization and Morphology ACS Sustainable
Chem. Eng. 2019, 7, 9, 8647-8659
https://doi.org/10.1021/acssuschemeng.9b00443
A Bossion, I Olazabal, R H Aguirresarobe, S Marina, J Martín, L Irusta, D Taton and H Sardon
Synthesis of self-healable waterborne isocyanate-free poly(hydroxyurethane)-based supramolecular networks by ionic interactions
Polym. Chem., 2019,10, 2723-2733
https://doi.org/10.1039/C9PY00439D
F Tabatabaee, M Khorasani, M Ebrahimi, A González, L Irusta and H Sardon
Synthesis and comprehensive study on industrially relevant flame retardant waterborne polyurethanes based on phosphorus chemistry
Prog. Org. Coat. 2019, 131, 397-406
https://doi.org/10.1016/j.porgcoat.2019.02.042
I Flores, A Martínez de Ilarduya, H Sardon , A J Müller and S Muñoz-Guerra
Synthesis of Aromatic–Aliphatic Polyesters by Enzymatic Ring Opening Polymerization of Cyclic Oligoesters and their Cyclodepolymerization for a Circular Economy ACS
ACS Appl. Polym. Mater. 2019, 1, 3, 321–325
https://doi.org/10.1021/acsapm.8b00265
A Basterretxea, E Gabirondo, C Jehanno, H Zhu, I Flores, A J Müller, A Etxeberria, D Mecerreyes, O Coulembier and H Sardon
Polyether Synthesis by Bulk Self-Condensation of Diols Catalyzed by Non-Eutectic Acid−Base Organocatalysts
ACS Sust. Chem. Eng., 2019, 7, 4, 4103–4111
https://doi.org/10.1021/acssuschemeng.8b05609
N Zivic, P K Kuroishi, F Dumur, D Gigmes, A P Dove, H Sardon
Recent Advances and Challenges in the Design of Organic Photoacid and Photobase Generators for Polymerizations
Angew. Chem., 2019, 58, 31, 10410-10422
https://doi.org/10.1002/anie.201810118
A Bossion, K V Heifferon, L Meabe, N Zivic, D Taton, J L Hedrick, T E Long, H Sardon*
Opportunities for organocatalysis in polymer synthesis via step-growth methods
Prog Polym Sci 2019, 90, 164-210
https://doi.org/10.1016/j.progpolymsci.2018.11.003
C Jehanno, M M Pérez-Madrigal, J Demarteau, H Sardon and A P. Dove
Organocatalysis for depolymerisation
Polym. Chem., 2019,10, 172-186
2018
E Verde-Sesto, N Goujon, H Sardon, P Ruiz, T Vu Huynh, F Elizalde, D Mecerreyes, M Forsyth, L A O´Dell
DNP NMR Studies of Crystalline Polymer Domains by Copolymerization with Nitroxide Radical Monomers
Macromolecules, 2018, 51 (20), 8046-8053
https://doi.org/10.1021/acs.macromol.8b01665
H Sardon and A P Dove
Plastic recycling with a difference
Science 2018, Vol. 360, Issue 6387, 380-381
https://doi.org.10.1126/science.aat4997
A Bossion, R H Aguirresarobe, L Irusta, D Taton, H Cramail, E Grau, D Mecerreyes, C Su, G Liu, A J Müller, H Sardon
Unexpected Synthesis of Segmented Poly(hydroxyurea-urethane)s from Dicyclic Carbonates and Diamines by Organocatalysis
Macromolecules, 2018, 51 (15), 5556-5566
https://doi.org/10.1021/acs.macromol.8b00731
A Y Yuen, A Bossion, A Veloso, D Mecerreyes, J L Hedrick, A P Dove and H Sardon
Efficient polymerization and post-modification of N-substituted eight-membered cyclic carbonates containing allyl groups
Polym. Chem., 2018,9, 2458-2467
https://doi.org/10.1039/C8PY00231B
I Flores, J Demarteau, A J Muller, A Etxeberria, L Irusta, F Bergman, C Koning, H Sardon
Screening of Different Organocatalysts for the Sustainable Synthesis of PET
Eur Polym J. 2018,104, 170-176
https://doi.org/10.1016/j.eurpolymj.2018.04.040
N Sadaba, M Salsamendi, N Casado, E Zuza, J Muñoz, J-R Sarasua, D Mecerreyes, D Mantione, C Detrembleur, H Sardon
Catechol End-Functionalized Polylactide by Organocatalyzed Ring-Opening Polymerization
Polymers 2018, 10(2), 155
https://doi.org/10.3390/polym10020155
L Meabe, T Vu Huynh, N Lago, H Sardon, C M Li, L A O’Dell, M Armand, M Forsyth, D Mecerreyes
Poly(ethylene oxide carbonates) solid polymer electrolytes for lithium batteries
Electrochimica Acta 2018, 367-375
https://doi.org/10.1016/j.electacta.2018.01.101
A Y Yuen, L Porcarelli, R H Aguirresarobe, A Sanchez-Sanche, I del Agua, U Ismailov, G G Malliaras, D Mecerreyes, E Ismailova, H Sardon
Biodegradable Polycarbonate Iongels for Electrophysiology Measurements
Polymers 2018, 10(9), 989
https://doi.org/10.3390/polym10090989
C Jehanno, I Flores, A P Dove, A J Müller, F Ruipérez, H Sardon
Organocatalaysed depolymerisation of PET in a fully sustainable cycle using thermally stable protic ionic salt
Green Chem. 2018, 20, 1205-1212
2017
Preparation of Biodegradable Cationic Polycarbonates and Hydrogels through the Direct Polymerization of Quaternized Cyclic Carbonates
ACS Biomater. Sci. Eng 2017, 3, 8, 1567–1575
https://doi.org/10.1021/acsbiomaterials.7b00335
L Meabe, H Sardon, D Mecerreyes
Hydrolytically degradable poly(ethylene glycol) based polycarbonates by organocatalyzed condensation
Eur. Polym. J. 2017, 95, 737-745
https://doi.org/10.1016/j.eurpolymj.2017.06.046
E Udabe, M Isik, H Sardon, L Irusta, M Salsamendi, Z Sun, Z Zheng, F Yan, D Mecerreyes
Antimicrobial polyurethane foams having cationic ammonium groups
J. Appl. polym Sci. 2017, 134, 45, 45473
https://doi.org/10.1002/app.45473
D Mantione, N Casado, A Sanchez-sanchez, H Sardon, D Mecerreyes
Easy-to-make carboxylic acid dioxythiophene monomer (ProDOT-COOH) and functional conductive polymers
Polym. Chem. 2017, 55, 17, 2721-2724
https://doi.org/10.1002/pola.28690
L I Roncoa, A Basterretxea, D Mantione, R H Aguirresarobe, R J Minari, L M Gugliotta, D Mecerreyes, H Sardon
Temperature responsive PEG-based polyurethanes “à la carte”
Polymer 2017, 122, 117-124
https://doi.org/10.1016/j.polymer.2017.06.043
X An, R H Aguirresarobe, L Irusta, F Ruipérez, J M Matxain, X Pan, N Aramburu, D Mecerreyes, H Sardon, Jian Zhu
Aromatic diselenide crosslinkers to enhance the reprocessability and self-healing of polyurethane thermosets
Polym. Chem. 2017, 8, 3641-3646
https://doi.org/10.1039/C7PY00448F
A Basterretxea, E Gabirondo, A Sanchez-Sanchez, A Etxeberria, O Coulembier, D Mecerreyes, H Sardon
Synthesis and characterization of poly (e-caprolactam-co-lactide) polyesteramides using Brønsted acid or Brønsted base organocatalyst
Eur. Polym. J 2017, 95, 650-659
https://doi.org/10.1016/j.eurpolymj.2017.05.023
D Mantione, I del Agua, W Schaafsma, M ElMahmoudy, I Uguz, A Sanchez-Sanchez, H Sardón, B Castro, G G Malliaras, David Mecerreyes
Low temperature cross-linking of PEDOT:PSS films using divinylsulfone
ACS applied and interfaces 2017, 9, 21, 18254–18262
https://doi.org/10.1021/acsami.7b02296
J P K Tan, D J Coady, H Sardon, A Yuen, S Venkataraman, A C Engler, R Ono, Y Y Yang, J L Hedrick
Broad spectrum macromolecular antimicrobials with biofilm disruption capability and in vivo efficacy
Adv. Health. Mater. 2017, 6, 16, 1601420
https://doi.org/10.1002/adhm.201601420
L Porcarelli, K Manojkumar, H Sardon, O Llorente, A S Shaplove, K Vijayakrishna, C Gerbaldi, D Mecerreyes
Single Ion Conducting Polymer Electrolytes Based on Versatile Polyurethanes
Electrochimica Acta 241 (2017) 526-534
https://doi.org/10.1016/j.electacta.2017.04.132
S Garmendia, D Mantione, S Alonso-de Castro, C Jehanno, L Lezama, J L Hedrick, D Mecerreyes, L Salassa and Ha Sardon
Polyurethane based organic macromolecular contrast agents (PU-ORCAs) for magnetic resonance imaging
Polym. Chem. 2017, 8, 2693-2701
https://doi.org/10.1039/C7PY00166E
Le eabe, N Lago, L Rubatat, C Li, A J Müller, H Sardon, M Armand, D Mecerreyes
Polycondensation as a Versatile Synthetic Route to Aliphatic Polycarbonates for Solid Polymer Electrolytes
Electrochimica Acta 237 (2017) 259–266
https://doi.org/10.1016/j.electacta.2017.03.217
Sofia M. Morozova, Alexander S. Shaplov, Elena I. Lozinskaya, Petr S. Vlasov, Haritz Sardon, David Mecerreyes and Yakov S. Vygodskii
Poly(ionic liquid)-based polyurethanes having imidazolium, ammonium, morpholinium, or pyrrolidonium cations
High Performance Polymers
https://doi.org/10.1177/0954008317701551
A Sanchez-Sanchez, I Rivilla, M Agirre, A Basterretxea, A Etxeberria, A Veloso, H Sardon, D Mecerreyes, Fernando P. Cossio
Enantioselective Ring-Opening Polymerization of rac-Lactide Dictated by Densely Substituted Aminoacids
J. Am. Chem. Soc., 2017, 139 (13), pp 4805–4814.
https://doi.org/10.1021/jacs.6b13080
S Morozova, A Shaplov, E Lozinskaya, D Mecerreyes, H Sardon, S Zulfiqar, F Suárez-García, Y Vygodskii
Ionic polyurethanes as new family of poly(ionic liquid)s for efficient CO2 capture
Macromolecules, 2017, 50 (7), pp 2814–2824
https://doi.org/10.1021/acs.macromol.6b02812
J M W Chan, R J Wojtecki, H Sardon, A L Z Lee, C E Smith, A Shkumatov, S Gao, H Kong, Y Y Yang, J L Hedrick
Self-Assembled, Biodegradable Magnetic Resonance Imaging Agents: Organic Radical-Functionalized Diblock Copolymers
ACS Macro Lett., 2017, 6, pp 176–180
https://doi.org/10.1021/acsmacrolett.6b00924
A Bossion, G O Jones, D Taton, D Mecerreyes, J L Hedrick, Z Y Ong, Y Y Yang, H Sardon
Non-Isocyanate Polyurethane Soft Nanoparticles Obtained by Surfactant-Assisted Interfacial Polymerization
Langmuir, 2017, 33 (8), pp 1959–1968
https://doi.org/10.1021/acs.langmuir.6b04242
H Daemi, M Barikani, H Sardon
Transition-metal-free synthesis of supramolecular ionic alginate-based polyurethanes
Carbohydr. Polym. 2017, 157, 1949-1954
https://doi.org/10.1016/j.carbpol.2016.11.086
M Isik, M Agirre, J Zarate, G Puras, D Mecerreyes, H Sardon, J L Pedraz
Amine Containing Cationic Methacrylate Copolymers as Efficient Gene Delivery Vehicles to Retinal Epithelial Cells
Polym. Sci., Part A 2017, 2, 280-287
https://doi.org/10.1002/pola.28376
M Ribeiro, M P Ferraz, F J Monteiro, M H Fernandes, M M Beppu, D Mantione, Haritz Sardon
Antibacterial silk fibroin/nanohydroxyapatite hydrogels with silver and gold nanoparticles for bone regeneration Nanomedicine
Nanomedicine 2017, 13(1,) 231-239
2016
A Basterretxea, Y Haga, A Sanchez-Sanchez, M Isik, L Irusta, M Tanaka, K Fukushima, Haritz Sardon
Biocompatibility and hemocompatibility evaluation of polyether urethanes synthesized using DBU organocatalyst
Eur. Polym. J. 2016, 84, 750-758
https://doi.org/10.1016/j.eurpolymj.2016.08.008
M Isik, J P K Tan, R J Ono, A Sanchez-Sanchez, D Mecerreyes, Y Y Yang, J L Hedrick, H Sardon
Tuning the antimicrobial properties of biodegradable polycarbonates by simple anion-exchange reactions
Macro. Biosci. 2016, 16, 1360-1367
https://doi.org/10.1002/mabi.201600090
J Fernández, H Amestoy, H Sardon, M Aguirre, A Larrañaga Varga, Jose-Ramon Sarasua
Effect of the molecular weight on the mechanical properties an crystallization of poly(ethylene brassylate) homopolymers
J Mech. Behav. Biomed. Mater. 2016, 64, 209-219
https://doi.org/10.1016/j.jmbbm.2016.07.031
J S Desport, D Mantione, M Moreno, H Sardón, M J Barandiaran, D Mecerreyes
Synthesis of three different galactose-based methacrylate monomers for the production of sugar-based polymers
Carbohydrate research 2016, 232, 50-54
https://doi.org/10.1016/j.carres.2016.06.008
D Mantione, I del Agua, W Schaafsma, J Diez-Garcia, B Castro, H Sardon, D Mecerreyes
Poly(3,4-ethylenedioxythiophene):GlycosAminGlycan (PEDOT:GAG) aqueous Dispersions: Towards Electrically Conductive Bioactive Materials for Neural Interfaces
Macro. Biosci 2016, 16, 1227-1238
https://doi.org/10.1002/mabi.201600059
A Sanchez-Sanchez, A Basterretxea, D Mantione, A Etxeberria, C Elizetxea, A de la Calle, S García-Arrieta, H Sardon, D Mecerreyes
Organo-mediated bulk polymerization of ε-Caprolactam and its Copolymerization with ε-Caprolactone using sulfonic acids
J. Polym. Sci., Part A 2016, 54, 2394-2402
https://doi.org/10.1002/pola.28114
J M W Chan, J P K Tan, A C Engler, X Ke, S Gao, C Yang, H Sardon, Y Y Yang, J L Hedrick
Anticancer Drug Loading of Degradable Polymeric Mixed Micelles via a Biomimetic Mechanism
Macromolecules, 2016, 49 (6), 2013–2021
https://doi.org/10.1021/acs.macromol.5b02784
M Isik, F Ruiperez, H Sardon, A Gonzalez, S Zulfiqar, D Mecerreyes
Innovative Poly(ionic liquid)s by the Polymerization of Deep Eutectic Monomers
Macro. Rapid Comm., 2016, 37, 1135–1142
https://doi.org/10.1002/marc.201600026
A Yuen, A Bossion, E Gómez-Bengoa, F Ruipérez, M Isik, J L Hedrick, D Mecerreyes, Y Y Yang, H Sardon
Room temperature synthesis of isocyanate free poly(hydroxyurethanes) using highly reactive N-substituted 8-membered cyclic carbonates.
Polym. Chem. 2016, 7, 2105-2111
https://doi.org/10.1039/C6PY00264A
H Daemi, S Rajabi-Zeleti, H Sardon, M Barikani, A Khademhosseini, H Baharvand
A Robust Super-Tough Biodegradable Elastomer Engineered by Supramolecular Ionic Interactions.
Biomaterials 2016, 84, 54-63
https://doi.org/10.1016/j.biomaterials.2016.01.025
W N Ottou, H Sardon, D Mecerreyes, J Vignolle, D Taton
Update and challenges in organo-mediated polymerization reactions
Prog. Polym. Sci. 2016, 56, 64–115
https://doi.org/10.1016/j.progpolymsci.2015.12.001
N Casado, G Hernández, H Sardon, D Mecerreyes
Current Trends in Redox Polymers for Energy and Nanomedicine
Prog. Polym. Sci. 2016, 52, 107-135
https://doi.org/10.1016/j.progpolymsci.2015.08.003
2015
S Venkataraman, V W L Ng, D J Coady, H W Horn, G O Jones, T S Fung, H Sardon, R M Waymouth, J L Hedrick, Y Y Yang
A Simple and Facile Approach to Functional Eight-Membered Aliphatic Cyclic Carbonates and Their Organo-catalytic Polymerization.
J. Am. Chem. Soc.2015, 137, 13851-13860
https://doi.org/10.1021/jacs.5b06355
M Isik, T Lonjaret, H Sardon, R Marcilla, T Herve, G G Malliaras, E Ismailova, D Mecerreyes
Cholinium Based Ion Gels as Electrolytes for Long-Term Cutaneous Recordings.
Mater. Chem. C, 2015, 3, 8942-8948
https://doi.org/10.1039/C5TC01888A
H Sardon, J P K Tan, J M W Chan, D Mantione, D Mecerreyes, J L Hedrick, Y Y Yang
Thermoresponsive Random Poly(ether urethane) based Nanoparticles with Tailorable LCSTs for Anticancer Drug Delivery.
Macromol. Rapid Comm. 2015, 36 (19), 1761-1767
https://doi.org/10.1002/marc.201500247
H Sardon, A Pascual, D Mecerreyes, D Taton, H Cramail, J L Hedrick
Synthesis of Polyurethanes using Organocatalysis: A Perspective
Macromolecules 2015, 48, 3153−3165
https://doi.org/10.1021/acs.macromol.5b00384
A Pascual, J P K Tan, A Yuen, J M W Chan, D J Coady, D Mecerreyes, J L Hedrick, Y Y Yang, H Sardon
Broad-Spectrum Antimicrobial Polycarbonate Hydrogels with Fast Degradability
Biomacromolecules 2015, 16 (4), 1169–1178
https://doi.org/10.1021/bm501836z
Q Xu, H Sardon, J M W Chan, J L Hedrick, Y Y Yang
Polyurethane-coated silica particles with broad-spectrum antibacterial properties
Polym. Chem. 2015,6, 2011–2022
https://doi.org/10.1039/C4PY01455C
H Sardon, A González, M J Fernández-Berridi, L. Irusta
Oxygen Barrier Properties of Waterborne Polyurethane/Silica Hybrids
J. Macromol. Sci. B. 2015, 54, 711-721
https://doi.org/10.1080/00222348.2015.1035613
J M W Chan, X Zhang, M K Brennan, H Sardon, A C Engler, C H Fox, C W Frank, R M Waymouth, J L Hedrick
Organocatalytic Ring-Opening Polymerization of Trimethylene Carbonate to Yield a Biodegradable Polycarbonate
J. Chem. Educ., 2015, 92 (4), 708–713
https://doi.org/10.1021/ed500595k
A Pascual, H Sardón, F Ruipérez, R Gracia, P Sudam, A Veloso, D Mecerreyes
Experimental and Computational Studies of Ring Opening Polymerization of Ethylene Brassylate Macrolactone and Copolymerization with ε-caprolactone and TBD-guanidine Organic Catalyst
J. Polym. Sci., Part A: Polym. Chem. 2015, 53 (4), 552-561
https://doi.org/10.1002/pola.27473
2014
V W L Ng, et al.
Antimicrobial hydrogels: a new weapon in the arsenal against multidrug-resistant infections
Adv. Drug Delivery Rev. 2014, 78, 46-62
https://doi.org/10.1016/j.addr.2014.10.028
M Isik, et al.
New amphiphilic block copolymers from lactic acid and cholinium building units
RSC Adv. 2014, 4, 53407-53410
https://doi.org/10.1039/C4RA10063H
A Pascual, et al.
Organocatalyzed Synthesis of Aliphatic Polyesters from Ethylene Brassylate: a Cheap and Renewable Macrolactone
ACS Macro Lett. 2014, 3 (9), 849-853
https://doi.org/10.1021/mz500401u
M Isik, et al.
Ionic Liquids and Cellulose: Dissolution, Chemical Modification and Preparation of New Celullosic Materials
Int. J. Mol. Sci. 2014, 15, 11922-11940
https://doi.org/10.3390/ijms150711922
J M W Chan, et al.
Chemically Modifiable N-Heterocycle-functionalized Polycarbonates as a Platform for Diverse Smart Biomimetic Nanomaterials
Chem. Sci. 2014, 5, 3294-3300
https://doi.org/10.1039/C4SC00789A
H Sardon, et al.
Polymer/silica nanohybrids by means of tetraethoxysilane sol–gel condensation onto waterborne polyurethane particles.
Prog. Org. Coat. 2014, 77, 1436–1442
http://dx.doi.org/10.1016/j.porgcoat.2014.04.032
H Sardon, et al.
Highly Tunable Polyurethanes: Organocatalyzed Polyaddition and Subsequent Post-polymerization Modification of Pentafluorophenyl Ester Sidechains.
Polym. Chem. 2014, 5, 3547-3550
https://doi.org/10.1039/C4PY00262H
D P Sanders, et al.
Synthesis of functionalized cyclic carbonate monomers using a versatile pentafluorophenyl carbonate intermediate.
Polym. Chem. 2014, 5(2), 327-329
https://doi.org/10.1039/C3PY01128C
2013
H Sardon, et al.
Organic Acid-Catalyzed Polyurethane Formation via a Dual-Activated Mechanism: Unexpected Preference of N‐Activation overO‐Activation of Isocyanates.
J. Am. Chem. Soc. 2013, 135, 16235−16241
https://dx.doi.org/10.1021/ja408641g
J M W Chan, et al.
Tetra-n-butylammonium Fluoride as an Efficient Transesterification Catalyst for the Functionalization of Cyclic Carbonates and Aliphatic Polycarbonates.
ACS Macro Lett., 2013, 2(10) 860–864
https://doi.org/10.1021/mz400334j
A Pascual, et al.
Organocatálisis: hacia una nueva generación de catalizadores para la síntesis de polímeros
Anales de Química 2013, 109(3), 173–181
H Sardon, et al.
Waterborne hybrid polyurethane coatings functionalized with (3-aminopropyl)triethoxysilane: Adhesion properties.
Prog. Org. Coat. 2013, 76, 1230–1235
https://doi.org/10.1016/j.porgcoat.2013.03.025
H Sardon, et al.
Homogeneous isocyanate-and catalyst-free synthesis of polyurethanes in aqueous media.
Green Chem., 2013, 15, (5), 1121-1126
https://doi.org/10.1039/C3GC40319J
D J Coady, et al.
Polymerizing Base Sensitive Cyclic Carbonates Using Acid Catalysis
ACS Macro Lett.2013,2(4),306-312
https://doi.org/10.1021/mz3006523
A C Engler, et al.
Accessing New Materials through Polymerization and Modification of a Polycarbonate with a Pendant Activated Ester.
Macromolecules 2013, 46 (4),1283-1290